Coal Geology & Exploration
Abstract
Objective For vitrinite with weak anisotropy, which proves uniaxial and optically negative, replacing random vitrinite reflectance (Rran) with the maximum vitrinite reflectance (Rmax) allows for the accurate correction of vitrinite reflectance suppression induced by anisotropy. However, as its anisotropy intensifies, vitrinite exhibits increasingly complex optical properties, rendering it challenging to reflect the thermal metamorphic temperature of vitrinite using Rmax. Methods This study investigated the strongly anisotropic vitrinite in coals and natural coke subjected to magma intrusion in the Shitai coal mine, Huaibei City, Anhui Province. Using a reflected-polarized light microscope (R-PLM), an ultra-high-definition scanning electron microscope (SEM), and tests on Rmax and the minimum vitrinite reflectance (Rmin), this study analyzed the microscopic textures, deep microfabrics, and optical properties of the vitrinite. Accordingly, the microscopic optical mechanisms underlying vitrinite reflectance suppression were explored. Results The strongly anisotropic vitrinite, formed by the contact metamorphism of magmas, contains flow-texture carbon and mosaic carbon, both composed of lamellar microfabrics. The lamellae in the carbon were uniaxial and optically negative (No > Ne), with the long axis No of the indicatrix parallel to the lamella surface and its short axis Ne perpendicular to the surface. The vitrinite exhibited the optical properties of pseudo-biaxial crystals in Kilby’s cross plot. The pseudo-biaxial crystals were formed by lamella folding. The underlying reason is that lamella folding changed the orientation of the lamellae’s reflected optical indicatrix (ROI) despite minimally influencing its morphology. Conclusions Lamella folding represents the direct cause of reflectance suppression in strongly anisotropic vitrinite. The Kilby’s cross plot serves as an effective method used to determine whether strong anisotropy induces vitrinite reflectance suppression. Replacing the average reflectance with Rmax corresponding to the maximum bireflectance (ΔRo) can correct reflectance suppression. This will help accurately determine the metamorphic grade of coals formed by magma intrusion-induced contact metamorphism through inversion.
Keywords
maximum reflectance of vitrinite, reflectance suppression, anisotropy, Kilby’s cross-plot, natural coke
DOI
10.12363/issn.1001-1986.25.12.0934
Recommended Citation
AN Yanfei, HE Shuyang, CHEN Kaixin,
et al.
(2026)
"Optical mechanisms behind vitrinite reflectance suppression caused by strong anisotropy: A case study of contact metamorphic coals,"
Coal Geology & Exploration: Vol. 54:
Iss.
4, Article 2.
DOI: 10.12363/issn.1001-1986.25.12.0934
Available at:
https://cge.researchcommons.org/journal/vol54/iss4/2
Reference
[1] LITTKE R,URAI J L,UFFMANN A K,et al. Reflectance of dispersed vitrinite in Palaeozoic rocks with and without cleavage:Implications for burial and thermal history modeling in the Devonian of Rursee area,northern Rhenish Massif,Germany[J]. International Journal of Coal Geology,2012,89:41−50.
[2] TAYLOR G H,TEICHMÜLLER M,DAVIS A,et al. Organic petrology[M]. Berlin:Gebrüder Borntraeger,1998.
[3] BURNHAM A K. Kinetic models of vitrinite,kerogen,and bitumen reflectance[J]. Organic Geochemistry,2019,131:50−59.
[4] PUSZ S,BORREGO A G,ALVAREZ D,et al. Application of reflectance parameters in the estimation of the structural order of coals and carbonaceous materials. Precision and bias of measurements derived from the ICCP structural working group[J]. International Journal of Coal Geology,2014,131:147−161.
[5] HOUSEKNECHT D W,WEESNER C M B. Rotational reflectance of dispersed vitrinite from the Arkoma Basin[J]. Organic Geochemistry,1997,26(3/4):191−206.
[6] FRINGS K,LUTZ R,DE WALL H,et al. Coalification history of the Stephanian Ciñera–Matallana pull–apart basin,NW Spain:Combining anisotropy of vitrinite reflectance and thermal modelling[J]. International Journal of Earth Sciences,2004,93(1):92−106.
[7] ZHANG Hui,ZHAO Weibo,WANG Huaichang,et al. Study on the suppression of vitrinite reflectance:A thermal simulation experiment[J]. ACS Omega,2024,9(3):41389−41395.
[8] DUBER S,PUSZ S,KWIECIŃSKA B K,et al. On the optically biaxial character and heterogeneity of anthracites[J]. International Journal of Coal Geology,2000,44(3/4):227−250.
[9] STACH E,TH MACKOWSKY M,TEICHMÜLLER M,et al. Stach’s textbook of coal petrology[M]. Berlin:Gebrüder Borntraeger,1982.
[10] ROSS J V,BUSTIN R M. Vitrinite anisotropy resulting from simple shear experiments at high temperature and high confining pressure[J]. International Journal of Coal Geology,1997,33(2):153−168.
[11] KELKER D,LANGENBERG W. Ellipsoid estimation in coal reflectance anisotropy[J]. Mathematical Geology,1997,29(2):185−198.
[12] KILBY W E. Recognition of vitrinite with non–uniaxial negative reflectance characteristics[J]. International Journal of Coal Geology,1988,9(3):267−285.
[13] MATUSZEWSKA A,PUSZ S,DUBER S. Evaluation of the structure of bituminous coal from Sośnica mine in the Upper Silesian Coal Basin (Poland) using reflectance indicating surface (RIS) parameters[J]. International Journal of Coal Geology,2015,152:177−188.
[14] 安燕飞,汪米娜,刘玲玲,等. 淮北袁店8煤岩浆热蚀变的微组构响应[J]. 煤炭学报,2017,42(11):2975−2980
AN Yanfei,WANG Mina,LIU Lingling,et al. Microfabrics response of coal to magma among coal seam Ⅷ in Yuandian mine of Huaibei City,China[J]. Journal of China Coal Society,2017,42(11):2975−2980
[15] AN Yanfei,LIU Lingling,WANG Mina,et al. Source and enrichment of toxic elements in coal seams around mafic intrusions:Constraints from pyrites in the Yuandian coal mine in Anhui,Eastern China[J]. Minerals,2018,8(4):164.
[16] SINGH A K,SHARMA M,SINGH M P. SEM and reflected light petrography:A case study on natural cokes from seam XIV,Jharia coalfield,India[J]. Fuel,2013,112:502−512.
[17] RIMMER S M,CRELLING J C,YOKSOULIAN L E. An occurrence of coked bitumen,Raton Formation,Purgatoire River Valley,Colorado,U. S. A[J]. International Journal of Coal Geology,2015,141/142:63–73.
[18] ZHAO Meixia,AN Yanfei,WANG Mina,et al. New genesis of natural coke around magmatic intrusion at the Shitai coalmine of Huaibei City,North China[J]. Acta Geologica Sinica (English Edition),2019,93(4):1158−1159.
[19] 安燕飞,陈凯鑫,王亚乔,等. 天然焦内炭微球显微光学特征、成因及其意义[J]. 煤田地质与勘探,2024,52(5):25−36
AN Yanfei,CHEN Kaixin,WANG Yaqiao,et al. Carbon microspheres in natural coke:Optical microscopic characteristics and their origin and implications[J]. Coal Geology & Exploration,2024,52(5):25−36
[20] KWIECIŃSKA B,PETERSEN H I. Graphite,semi–graphite,natural coke,and natural char classification:ICCP system[J]. International Journal of Coal Geology,2004,57(2):99−116.
[21] ASTM D2798–11. Standard test method for microscopical determination of the vitrinite reflectance of coal[S]. 2011.
[22] 安燕飞,黄健欣,郑硕,等. 淮北石台煤矿接触变质煤速热碳化的微组构解译[J]. 地质学报,2024,98(1):280−296
AN Yanfei,HUANG Jianxin,ZHENG Shuo,et al. Ultra–microfabrics interpretation of the rapid thermal carbonization of magma contact metamorphic coal in the Shitai coal mine,North China[J]. Acta Geologica Sinica,2024,98(1):280−296
[23] 姚伯元,李德平. 煤镜质体反射率测定条件与测定值分析[J]. 煤田地质与勘探,2013,41(5):11−16
YAO Boyuan,LI Deping. Determination conditions and measured value analysis of vitrinite reflectance[J]. Coal Geology & Exploration,2013,41(5):11−16
[24] 赵俊峰,刘池洋,王晓梅. 镜质体反射率测定结果的影响因素[J]. 煤田地质与勘探,2004,32(6):15−18
ZHAO Junfeng,LIU Chiyang,WANG Xiaomei. The factors influencing the measurement results of vitrinite reflectance[J]. Coal Geology & Exploration,2004,32(6):15−18
[25] 张术根. 矿相学[M]. 长沙:中南大学出版社,2014.
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