Coal Geology & Exploration
Abstract
Background Since the beginning of the Industrial Revolution, excessive CO2 emissions have aggravated the greenhouse effect. Against this backdrop, CO2 capture, utilization, and storage (CCUS) technology has emerged as a critical countermeasure. Particularly, geologic CO2 storage holds enormous application potential. China has implemented a demonstration project of geologic CO2 storage in saline aquifers located in the Enping Sag, Pearl River Mouth Basin. Nevertheless, this sag exhibits formation dip angles and widely distributed fracture zones, which affect CO2 migration and storage. Methods Focusing on the Enping Sag, this study established a two-dimensional model of the saline aquifer with a fracture zone using the TOUGH3 software. Using the established model, this study analyzed the impacts of factors, including formation dip angle, fracture zone location, and injection pressure, on the distributions of formation pressure, free CO2, and dissolved CO2, as well as the time-varying amounts of storage of various phases of CO2 within reservoirs, during CO2 storage. Through comparison of the amounts of CO2 storage in the reservoirs, the influential mechanisms of varying factors on the upward migration and leakage of CO2 were elucidated. Additionally, by analyzing the proportions of the amounts of dissolved CO2 storage in varying reservoirs, this study revealed the role of different factors in determining the storage safety.Results and Conclusions During CO2 injection, the fracture zone could release the pressure from the lower reservoir to the upper reservoir, thus alleviating the pressure rise in the middle cap rocks caused by the accumulation of free CO2. At 100 a, CO2 storage in the upper reservoir proved safer than that in the lower reservoir. In the formation at dip angles ranging from 0° to 2°, a higher formation dip angle led to a longer migration distance of free CO2 in the reservoirs towards the updip direction. After 70 a, the risks of the upward migration and leakage of CO2 were reduced. Between 20 a and 100 a, the safety of CO2 storage in the reservoirs was enhanced, especially in the upper reservoir. Within a horizontal distance range of 50‒200 m from the injection well, the risks of the upward migration and leakage of CO2 decreased with an increase in the horizontal distance between the fracture zone and the injection well. However, the safety of CO2 storage in the reservoirs decreased at 100 a. At injection pressure ranging from 16.5 MPa to 19.5 MPa, an increase in injection pressure corresponded to an increased total amount of CO2 storage but a decreased proportion of the amount of the dissolved CO2 storage at 100 a, with such storage tending to be unstable. At an injection pressure of 18.0 MPa, the proportion of the amount of CO2 storage in the lower reservoir reached its maximum (42.21%), suggesting the lowest risks of the upward migration and leakage of CO2. Among the three factors influencing CO2 storage safety, formation dip angle and injection pressure determine the safety of CO2 storage in the upper and lower reservoirs, respectively, while the horizontal distance between the fracture zone and the injection well serves as a major factor affecting the upward migration and leakage of CO2. The results of this study will provide a theoretical basis for CO2 storage projects in saline aquifers with fracture zones and deepen the understanding of the mechanisms behind CO2 storage in analogous geological settings. Accordingly, the results will contribute to the large-scale application and industrial advancement of geologic CO2 storage while also providing support for the attainment of peak carbon dioxide emissions and carbon neutrality.
Keywords
CO2 storage, CO2 capture, utilization, and storage (CCUS) technology, Enping Sag, saline aquifer, fracture zone, formation dip angle, injection pressure
DOI
10.12363/issn.1001-1986.25.07.0564
Recommended Citation
YU Tao, LI Xiwen, YANG Yunshi,
et al.
(2026)
"Numerical simulations of the safety of geologic CO2 storage in saline aquifers in the Enping Sag, Pearl River Mouth Basin,"
Coal Geology & Exploration: Vol. 54:
Iss.
1, Article 20.
DOI: 10.12363/issn.1001-1986.25.07.0564
Available at:
https://cge.researchcommons.org/journal/vol54/iss1/20
Reference
[1] LYU Xinrun,ZHANG Shicheng,MA Xinfang,et al. Numerical study of non–isothermal flow and wellbore heat transfer characteristics in CO2 fracturing[J]. Energy,2018,156:555−568.
[2] 孙玉景,周立发,李越. CO2海洋封存的发展现状[J]. 地质科技情报,2018,37(4):212−218
SUN Yujing,ZHOU Lifa,LI Yue. Development status of CO2 marine sequestration[J]. Geological Science and Technology Information,2018,37(4):212−218
[3] LINDEBERG E,WESSEL–BERG D. Vertical convection in an aquifer column under a gas cap of CO2[J]. Energy Conversion and Management,1997,38:S229−S234.
[4] BENTHAM M,KIRBY G. CO2 storage in saline aquifers[J]. Oil & Gas Science and Technology,2005,60(3):559−567.
[5] LI Hangyu,LAU H C,WEI Xiaofang,et al. CO2 storage potential in major oil and gas reservoirs in the northern South China Sea[J]. International Journal of Greenhouse Gas Control,2021,108:103328.
[6] MADDINELLI G,BRANCOLINI A. MRI as a tool for the study of waterflooding processes in heterogeneous cores[J]. Magnetic Resonance Imaging,1996,14(7/8):915−917.
[7] GUNTER W D,WIWEHAR B,PERKINS E H. Aquifer disposal of CO2–rich greenhouse gases:Extension of the time scale of experiment for CO2–sequestering reactions by geochemical modelling[J]. Mineralogy and Petrology,1997,59(1):121−140.
[8] BRADSHAW J,BACHU S,BONIJOLY D,et al. CO2 storage capacity estimation:Issues and development of standards[J]. International Journal of Greenhouse Gas Control,2007,1(1):62−68.
[9] DIAO Yujie,MA Xin,ZHANG Chenglong,et al. CO2 geological storage in sedimentary basins:An update on the potential and suitability evaluation and a field test[J]. Energy Geoscience,2025,6(1):100369.
[10] 陈建文,王嘹亮,王平康,等. 中国海域沉积盆地咸水层二氧化碳地质封存潜力[J]. 海洋地质与第四纪地质,2024,44(3):98−114
CHEN Jianwen,WANG Liaoliang,WANG Pingkang,et al. Carbon dioxide geological storage potential in saline aquifer of sedimentary basins in China Sea[J]. Marine Geology & Quaternary Geology,2024,44(3):98−114
[11] 米立军. 全球海上CO2封存现状及中国近海机遇与挑战[J]. 中国海上油气,2023,35(1):123−135
MI Lijun. Current status of global CO2 ocean sequestration and opportunities and challenges in China offshore areas[J]. China Offshore Oil and Gas,2023,35(1):123−135
[12] 衣华磊,郭欣,贾津耀,等. 恩平15–1油田开发CO2回注封存工程方案研究[J]. 中国海上油气,2023,35(1):163−169
YI Hualei,GUO Xin,JIA Jinyao,et al. Research on CO2 re–injection and storage engineering scenario of EP15–1 oilfield development[J]. China Offshore Oil and Gas,2023,35(1):163−169
[13] 施和生,何敏,张丽丽,等. 珠江口盆地(东部)油气地质特征、成藏规律及下一步勘探策略[J]. 中国海上油气,2014,26(3):11−22
SHI Hesheng,HE Min,ZHANG Lili,et al. Hydrocarbon geology,accumulation pattern and the next exploration strategy in the eastern Pearl River Mouth Basin[J]. China Offshore Oil and Gas,2014,26(3):11−22
[14] 陈维涛,孙珍,何敏,等. 珠江口盆地中中新世SQ14. 8层序–沉积演化及其地质意义[J]. 大地构造与成矿学,2021,45(5):875–891.
CHEN Weitao,SUN Zhen,HE Min,et al. The mid–Miocene stratigraphic–depositional evolution recorded by the SQ14. 8 layer in Pearl River Mouth Basin and its geological significances[J]. Geotectonica et Metallogenia,2021,45(5):875–891.
[15] 何金海,吴静,白海军,等. 珠江口盆地恩平凹陷油气沿断层走向运移模式[J]. 海洋地质前沿,2022,38(8):55−66
HE Jinhai,WU Jing,BAI Haijun,et al. Mode of oil–gas migration along fault strike in Enping Sag of Pearl River Mouth Basin[J]. Marine Geology Frontiers,2022,38(8):55−66
[16] 石晓光. 珠江口盆地恩平凹陷新生代断裂特征与盆地成因[J]. 海洋地质前沿,2021,37(12):1−9
SHI Xiaoguang. Cenozoic fault characteristics and basin genesis of the Enping Sag,Pearl River Mouth Basin[J]. Marine Geology Frontiers,2021,37(12):1−9
[17] KUMAR A,OZAH R,NOH M,et al. Reservoir simulation of CO2 storage in deep saline aquifers[J]. SPE Journal,2005,10(3):336−348.
[18] PRUESS K,NORDBOTTEN J. Numerical simulation studies of the long–term evolution of a CO2 plume in a saline aquifer with a sloping caprock[J]. Transport in Porous Media,2011,90(1):135−151.
[19] WANG Fugang,JING Jing,XU Tianfu,et al. Impacts of stratum dip angle on CO2 geological storage amount and security[J]. Greenhouse Gases:Science and Technology,2016,6(5):682−694.
[20] JING Jing,YANG Yanlin,CHENG Jianmei,et al. Analysis of the effect of formation dip angle and injection pressure on the injectivity and migration of CO2 during storage[J]. Energy,2023,280:128021.
[21] 朱定伟,彭光荣,张忠涛,等. 油气“穿断运移”模式、评价方法与应用:以珠江口盆地恩平凹陷为例[J]. 大地构造与成矿学,2021,45(1):140−147
ZHU Dingwei,PENG Guangrong,ZHANG Zhongtao,et al. Model of oil–gas cross–fault migration,evaluation and application:A case in the Enping Sag of Pearl River Mouth Basin[J]. Geotectonica et Metallogenia,2021,45(1):140−147
[22] 吴娟,叶加仁,施和生,等. 恩平凹陷中央断裂构造带超压发育及成藏意义[J]. 中南大学学报(自然科学版),2013,44(7):2801−2811
WU Juan,YE Jiaren,SHI Hesheng,et al. Overpressure forming and its effect on petroleum accumulation in central faulted structural belt of Enping Depression,China[J]. Journal of Central South University (Science and Technology),2013,44(7):2801−2811
[23] 吴静,丁琳,张晓钊,等. 珠江口盆地恩平凹陷海相三角洲岩性圈闭勘探的关键技术[J]. 长江大学学报(自然科学版),2022,19(1):44−53
WU Jing,DING Lin,ZHANG Xiaozhao,et al. Key technologies of lithologic trap exploration in marine delta of Enping Sag in Pearl River Mouth Basin[J]. Journal of Yangtze University (Natural Science Edition),2022,19(1):44−53
[24] 王华,戴建文,柴愈坤,等. 珠江口盆地新近纪相对海平面变化精细表征及其对三角洲沉积演化的反映:以恩平凹陷恩平A油田韩江组–珠江组为例[J]. 吉林大学学报(地球科学版),2024,54(2):359−370
WANG Hua,DAI Jianwen,CHAI Yukun,et al. Detailed characterization of Neogene relative sea level change in Pearl River Mouth Basin and its control over delta sedimentary evolution:Taking Hanjiang Formation and Zhujiang Formation of oilfield A in Enping Sag as an example[J]. Journal of Jilin University (Earth Science Edition),2024,54(2):359−370
[25] 刘志峰,吴克强,柯岭,等. 珠江口盆地珠一坳陷北部洼陷带油气成藏主控因素[J]. 石油与天然气地质,2017,38(3):561−569
LIU Zhifeng,WU Keqiang,KE Ling,et al. Main factors controlling hydrocarbon accumulation in northern subsag belt of the Zhu–1 Depression,Pearl River Mouth Basin[J]. Oil & Gas Geology,2017,38(3):561−569
[26] 可行,陈建文,龚建明,等. 珠江口盆地二氧化碳地质封存条件及源汇匹配性分析[J]. 海洋地质与第四纪地质,2023,43(2):55−65
KE Xing,CHEN Jianwen,GONG Jianming,et al. Assessment on geological condition for carbon dioxide sequestration and source–sink matching in the Pearl River Mouth Basin[J]. Marine Geology & Quaternary Geology,2023,43(2):55−65
[27] 张文昭,张厚和,李春荣,等. 珠江口盆地油气勘探历程与启示[J]. 新疆石油地质,2021,42(03):346−352+363
ZHANG Wenzhao,ZHANG Houhe,LI Chunrong,et al. Petroleum Exploration History and Enlightenment in Pearl River Mouth Basin[J]. Xinjiang Petroleum Geology,2021,42(03):346−352+363
[28] 陈建亮,施和生,舒誉,等. 测井盖层评价方法在珠一坳陷的应用[J]. 中国海上油气,2007,19(3):157−161
CHEN Jianliang,SHI Hesheng,SHU Yu,et al. The application of seal evaluation method with log data in Zhu Ⅰ Depression,Pearl River Mouth Basin[J]. China Offshore Oil and Gas,2007,19(3):157−161
[29] 钟志洪,施和生,朱明,等. 珠江口盆地构造–地层格架及成因机制探讨[J]. 中国海上油气,2014,26(5):20−29
ZHONG Zhihong,SHI Hesheng,ZHU Ming,et al. A discussion on the tectonic–stratigraphic framework and its origin mechanism in Pearl River Mouth Basin[J]. China Offshore Oil and Gas,2014,26(5):20−29
[30] 张向涛,彭光荣,朱定伟,等. 珠江口盆地恩平凹陷CO2成藏特征与成藏过程[J]. 大地构造与成矿学,2021,45(1):211−218
ZHANG Xiangtao,PENG Guangrong,ZHU Dingwei,et al. Characteristics and processes of CO2 accumulation in the Enping Sag,Pearl River Mouth Basin[J]. Geotectonica et Metallogenia,2021,45(1):211−218
[31] 苏芝懿,李志刚,代向明,等. 裂陷盆地正断层几何结构对沉积充填的控制作用:以珠江口盆地陆丰、恩平凹陷为例[J]. 大地构造与成矿学,2025,49(5):1085−1100
SU Zhiyi,LI Zhigang,DAI Xiangming,et al. Rift basin fault structures and their influence on sedimentary systems:A case study of the Lufeng and Enping Sags in the Pearl River Mouth Basin[J]. Geotectonica et Metallogenia,2025,49(5):1085−1100
[32] 付广,李建民. 断裂对油气富集程度的控制作用[J]. 断块油气田,2014,21(6):707−710
FU Guang,LI Jianmin. Control effect of faults to oil–gas enrichment degree[J]. Fault–Block Oil & Gas Field,2014,21(6):707−710
[33] JUNG Y J,PAU G S H,FINSTERLE S,et al. TOUGH3:A new efficient version of the TOUGH suite of multiphase flow and transport simulators[J]. Computers & Geosciences,2017,108:2−7.
[34] PRUESS K,GARCÍA J,KOVSCEK T,et al. Code intercomparison builds confidence in numerical simulation models for geologic disposal of CO2[J]. Energy,2004,29(9/10):1431−1444.
[35] 张功成,陈国俊,张厚和,等. “源热共控”中国近海盆地油气田“内油外气”有序分布[J]. 沉积学报,2012,30(1):1−19
ZHANG Gongcheng,CHEN Guojun,ZHANG Houhe,et al. Regular distribution of inside–oil fields and outside–gas fields controlled by source rocks and heat in China offshore basins[J]. Acta Sedimentologica Sinica,2012,30(1):1−19
[36] COREY A T. The interrelation between gas and oil relative permeability[J]. Producers Monthly,1954,19:38−41.
[37] VAN GENUCHTEN M T. A closed–form equation for predicting the hydraulic conductivity of unsaturated soils[J]. Soil Science Society of America Journal,1980,44(5):892−898.
[38] MUALEM Y. A new model for predicting the hydraulic conductivity of unsaturated porous media[J]. Water Resources Research,1976,12(3):513−522.
[39] 舒梁锋,张向涛,张忠涛,等. 珠江口盆地白云南洼珠海组陆架边缘三角洲沉积体系演化[J]. 沉积学报,2022,40(3):825−837
SHU Liangfeng,ZHANG Xiangtao,ZHANG Zhongtao,et al. Evolution of the shelf–margin delta sedimentary system in the Zhuhai Formation in the south subsag of Baiyun Sag,Pearl River Mouth Basin[J]. Acta Sedimentologica Sinica,2022,40(3):825−837
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