•  
  •  
 

Coal Geology & Exploration

Abstract

Objectives and Methods Deep saline aquifers represent ideal spaces for geologic CO2 sequestration while also featuring high geothermal gradients and abundant geothermal resources. The combination of CO2 sequestration and geothermal energy extraction holds great significance for enhancing the CO2 sequestration effect and achieving integrated resource development of deep saline aquifers. Therefore, this study proposed a development approach that combined CO2 sequestration with geothermal energy extraction in deep saline aquifers and established a thermo-hydro-chemical coupling numerical simulation model of the gas-water two-phase flow. Accordingly, it explored the optimal injection mode, production and injection well patterns, and injection and production parameters Results and Conclusions Extracting formation water and geothermal energy during CO2 injection can effectively delay the rise in formation pressure while also providing more spaces for CO2 storage, with the CO2 storage capacity increasing by 16 500 t. After the depletion of movable water, further geothermal energy extraction with CO2 as the work fluid yielded an additional 6.60 MJ of heat while further increasing the CO2 storage capacity by 30 800 t. Geochemical reactions occurred during CO2 injection, increasing reservoir porosity and permeability by 0.0022 and 0.43×10–3μm2, respectively. This creates favorable conditions for continuous CO2 injection and geothermal energy extraction. Intermittent injection can delay the rise in the formation pressure to the greatest extent, identified as the optimal injection mode. It is recommended that production and injection wells should be arranged in the same aquifer and that more injection wells should be arranged in the structurally lower parts of reservoirs compared to production wells. The optimal injection and production parameters include an injection rate of 10 000 m3/day, an injection-to-production rate ratio of 0.8, an injection cycle of three months, and a cyclic injection-to-production time ratio of 1. The proposed new development approach offers a novel philosophy for geologic CO2 sequestration in deep saline aquifers while also serving as a valuable reference for reaching the goals of carbon neutrality and peak carbon dioxide emissions and promoting efficient, collaborative resource development.

Keywords

deep saline aquifer, geothermal energy, geologic CO2 sequestration, numerical simulation, injection mode, well pattern, selection of optimal parameters

DOI

10.12363/issn.1001-1986.25.05.0376

Reference

[1] 中国21世纪议程管理中心,全球碳捕集与封存研究院,清华大学. 中国碳捕集利用与封存年度报告(2023)[R/OL]. (2023-07-14) (2023-11-10) [2025-04-25]. https://wwwglobalccsinstitutecom/wp–content/uploads/2023/03/CCS–Progress–in–China–CNpdf.

[2] IEA. CO2 emissions in 2022[R/OL]. (2023-11-10) [2025-04-25]. https://ieablobcorewindowsnet/assets/3c8fa115–35c4–4474–b237–1b00424c8844/CO2Emissionsin2022pdf.

[3] 卢义玉,周军平,鲜学福,等. 超临界CO2强化页岩气开采及地质封存一体化研究进展与展望[J]. 天然气工业,2021,41(6):60−73.

LU Yiyu,ZHOU Junping,XIAN Xuefu,et al. Research progress and prospect of the integrated supercritical CO2 enhanced shale gas recovery and geological sequestration[J]. Natural Gas Industry,2021,41(6):60−73.

[4] 张烈辉,曹成,文绍牧,等. 碳达峰碳中和背景下发展CO2–EGR的思考[J]. 天然气工业,2023,43(1):13−22.

ZHANG Liehui,CAO Cheng,WEN Shaomu,et al. Thoughts on the development of CO2–EGR under the background of carbon peak and carbon neutrality[J]. Natural Gas Industry,2023,43(1):13−22.

[5] 李阳,王锐,赵清民,等. 含油气盆地咸水层二氧化碳封存潜力评价方法[J]. 石油勘探与开发,2023,50(2):424−430.

LI Yang,WANG Rui,ZHAO Qingmin,et al. A CO2 storage potential evaluation method for saline aquifers in a petroliferous basin[J]. Petroleum Exploration and Development,2023,50(2):424−430.

[6] ALI F,NEGASH B M,RIDHA S,et al. A review on the interfacial properties of caprock/CO2/brine system–implications for structural integrity of deep saline aquifers during geological carbon storage[J]. Earth–Science Reviews,2023,247:104600.

[7] BICKLE M J. Geological carbon storage[J]. Nature Geoscience,2009,2(12):815−818.

[8] FURRE A K,EIKEN O,ALNES H,et al. 20 years of monitoring CO2–injection at Sleipner[C]//Proceedings of the 13th International Conference on Greenhouse Gas Control Technologies (GHGT). Lausanne:IEAGHG,2016

[9] MICHAEL K,GOLAB A,SHULAKOVA V,et al. Geological storage of CO2 in saline aquifers:A review of the experience from existing storage operations[J]. International Journal of Greenhouse Gas Control,2010,4(4):659−667.

[10] RUTQVIST J,VASCO D W,MYER L. Coupled reservoir–geomechanical analysis of CO2 injection and ground deformations at In Salah,Algeria[J]. International Journal of Greenhouse Gas Control,2010,4(2):225−230.

[11] LI Qi,LIU Guizhen,LIU Xuehao,et al. Application of a health,safety,and environmental screening and ranking framework to the Shenhua CCS project[J]. International Journal of Greenhouse Gas Control,2013,17:504−514.

[12] ZHANG Keni,XIE Jian,LI Cai,et al. A full chain CCS demonstration project in northeast Ordos Basin,China:Operational experience and challenges[J]. International Journal of Greenhouse Gas Control,2016,50:218−230.

[13] 黄永辉,庞忠和,程远志,等. 深层含水层地下储热技术的发展现状与展望[J]. 地学前缘,2020,27(1):17−24.

HUANG Yonghui,PANG Zhonghe,CHENG Yuanzhi,et al. The development and outlook of the deep aquifer thermal energy storage (deep–ATES)[J]. Earth Science Frontiers,2020,27(1):17−24.

[14] 石宇,崔启亮,杨子江,等. 基于灰色关联度分析和多目标优化的浅层含水层储热性能整体优化[J]. 天然气工业,2023,43(6):156−168.

SHI Yu,CUI Qiliang,YANG Zijiang,et al. Optimizing the thermal energy storage performance of shallow aquifer based on gray correlation analysis and multi–objective optimization[J]. Natural Gas Industry,2023,43(6):156−168.

[15] LI Qi,WEI Yani,LIU Guizhen,et al. CO2–EWR:A cleaner solution for coal chemical industry in China[J]. Journal of Cleaner Production,2015,103:330−337.

[16] XU Mao,ZHANG Xian,SHEN Shuo,et al. Assessment of potential,cost,and environmental benefits of CCS–EWR technology for coal–fired power plants in Yellow River Basin of China[J]. Journal of Environmental Management,2021,292:112717.

[17] 蒋恕,张凯,杜凤双,等. 二氧化碳地质封存及提高油气和地热采收率技术进展与展望[J]. 地球科学,2023,48(7):2733−2749.

JIANG Shu,ZHANG Kai,DU Fengshuang,et al. Progress and prospects of CO2 storage and enhanced oil,gas and geothermal recovery[J]. Earth Science,2023,48(7):2733−2749.

[18] LI Yi,SUN Ruikang,LI Yi,et al. An enhanced role understanding of geothermal energy on compressed air energy storage in aquifers considering the underground processes[J]. Journal of Energy Storage,2021,44:103483.

[19] CUI Guodong,REN Shaoran,DOU Bin,et al. Geothermal energy exploitation from depleted high–temperature gas reservoirs by recycling CO2:The superiority and existing problems[J]. Geoscience Frontiers,2021,12(6):101078.

[20] BROWN D W. A hot dry rock geothermal energy concept utilizing supercritical CO2 instead of water[C]//Proceedings of the 25th Workshop on Geothermal Reservoir Engineering. Stanford:Stanford University,2000.

[21] ZHANG Fuzhen,JIANG Peixue,XU Ruina. System thermodynamic performance comparison of CO2–EGS and water–EGS systems[J]. Applied Thermal Engineering,2013,61(2):236−244.

[22] 任韶然,崔国栋,李德祥,等. 注超临界CO2开采高温废弃气藏地热机制与采热能力分析[J]. 中国石油大学学报(自然科学版),2016,40(2):91−98.

REN Shaoran,CUI Guodong,LI Dexiang,et al. Development of geothermal energy from depleted high temperature gas reservoir via supercritical CO2 injection[J]. Journal of China University of Petroleum (Edition of Natural Science),2016,40(2):91−98.

[23] LI Jiawei,SUN Zhixue,ZHANG Yin,et al. Investigations of heat extraction for water and CO2 flow based on the rough–walled discrete fracture network[J]. Energy,2019,189:116184.

[24] GUO Tiankui,GONG Facheng,WANG Xiaozhi,et al. Performance of enhanced geothermal system (EGS) in fractured geothermal reservoirs with CO2 as working fluid[J]. Applied Thermal Engineering,2019,152:215−230.

[25] 石宇,宋先知,李根生,等. 多分支井地热系统CO2与水的取热效果对比[J]. 天然气工业,2021,41(11):179−190.

SHI Yu,SONG Xianzhi,LI Gensheng,et al. Comparison of heat extraction performance between CO2 and water in a multilateral–well geothermal system[J]. Natural Gas Industry,2021,41(11):179−190.

[26] WANG Zhiqiang,LI Hangyu,LIU Shuyang,et al. Risk evaluation of CO2 leakage through fracture zone in geological storage reservoir[J]. Fuel,2023,342:127896.

[27] COLLINS D A,NGHIEM L X,LI Y K,et al. An efficient approach to adaptive–implicit compositional simulation with an equation of state[J]. SPE Reservoir Engineering,1992,7(2):259−264.

[28] MILLER C C. The Stokes–Einstein law for diffusion in solution[J]. Proceedings of the Royal Society A:Mathematical,Physical and Engineering Sciences,1924,106(740):724−749.

[29] PENG Dingyu,ROBINSON D B. A new two–constant equation of state[J]. Industrial & Engineering Chemistry Fundamentals,1976,15(1):59−64.

[30] LI Y K,NGHIEM L X. Phase equilibria of oil,gas and water/brine mixtures from a cubic equation of state and Henry’s law[J]. The Canadian Journal of Chemical Engineering,1986,64(3):486−496.

[31] CHAI Maojie,CHEN Zhangxin,NOUROZIEH H,et al. Numerical simulation of large–scale seasonal hydrogen storage in an anticline aquifer:A case study capturing hydrogen interactions and cushion gas injection[J]. Applied Energy,2023,334:120655.

[32] BURNSIDE N M,NAYLOR M. Review and implications of relative permeability of CO2/brine systems and residual trapping of CO2[J]. International Journal of Greenhouse Gas Control,2014,23:1−11.

[33] JIA Wei,MCPHERSON B,PAN Feng,et al. Impact of three–phase relative permeability and hysteresis models on forecasts of storage associated with CO2–EOR[J]. Water Resources Research,2018,54(2):1109−1126.

[34] LAND C S. Calculation of imbibition relative permeability for two– and three–phase flow from rock properties[J]. Society of Petroleum Engineers Journal,1968,8(2):149−156.

[35] AGHABOZORGI S,SOHRABI M. Generalised model for simulation of two– and three–phase cycle–dependent hysteresis in sandstones[J]. Fuel,2022,310:122328.

[36] BETHKE C M. Geochemical reaction modeling:Concepts and applications[M]. Oxford:Oxford University Press,1996.

[37] KENYON D. Third SPE comparative solution project:Gas cycling of retrograde condensate reservoirs[J]. Journal of Petroleum Technology,1987,39(8):981−997.

[38] PEACEMAN D W. Interpretation of well–block pressures in numerical reservoir simulation with nonsquare grid blocks and anisotropic permeability[J]. Society of Petroleum Engineers Journal,1983,23(3):531−543.

[39] VINSOME P K W,WESTERVELD J. A simple method for predicting cap and base rock heat losses In’ thermal reservoir simulators[J]. Journal of Canadian Petroleum Technology,1980,19(3):PETSOC–80–03–04.

[40] ZOBACK M D,GORELICK S M. Earthquake triggering and large–scale geologic storage of carbon dioxide[J]. Proceedings of the National Academy of Sciences of the United States of America,2012,109(26):10164−10168.

[41] BIRKHOLZER J T,OLDENBURG C M,ZHOU Quanlin. CO2 migration and pressure evolution in deep saline aquifers[J]. International Journal of Greenhouse Gas Control,2015,40:203−220.

[42] KOU Zuhao,XIN Yuchen,WANG Heng,et al. Exploring CO2 storage with impurities in deep saline aquifers through computational experiments[J]. Renewable Energy,2024,223:120085.

[43] LI Danchen,SARAJI S,JIAO Zunsheng,et al. CO2 injection strategies for enhanced oil recovery and geological sequestration in a tight reservoir:An experimental study[J]. Fuel,2021,284:119013.

[44] EDLMANN K,HINCHLIFFE S,HEINEMANN N,et al. Cyclic CO2–H2O injection and residual trapping:Implications for CO2 injection efficiency and storage security[J]. International Journal of Greenhouse Gas Control,2019,80:1−9.

[45] ZOU A,DURLOFSKY L J. Integrated framework for constrained optimization of horizontal/deviated well placement and control for geological CO2 storage[J]. SPE Journal,2023,28(5):2462−2481.

[46] 张烈辉,杨军,熊钰,等. 不同注采方式下CO2埋存与驱油效果优化评价[J]. 天然气工业,2008,28(8):102−104.

ZHANG Liehui,YANG Jun,XIONG Yu,et al. Optimizing evaluation of CO2 storage and flooding effect under different injection–production modes[J]. Natural Gas Industry,2008,28(8):102−104.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.