Impacts of diamond particle sizes on performance of Ni-Cu superhydrophobic coatings on drilling tool surfaces

Authors

WEN Qi, Faculty of Engineering, China University of Geosciences, Wuhan 430074, ChinaFollow
LI Tao, Faculty of Engineering, China University of Geosciences, Wuhan 430074, China
DUAN Longchen, Faculty of Engineering, China University of Geosciences, Wuhan 430074, China; National Center for International Research on Deep Earth Drilling and Resource Development, Wuhan 430074, China
PAN Bingsuo, Faculty of Engineering, China University of Geosciences, Wuhan 430074, China; National Center for International Research on Deep Earth Drilling and Resource Development, Wuhan 430074, ChinaFollow

Abstract

Objective Applying superhydrophobic coatings on drilling tool surfaces can effectively alleviate the challenges posed by drill bit balling and core barrel blockage. However, the limited mechanical stability of superhydrophobic coatings has somewhat hindered their widespread application in practical operations. Methods To improve the durability of superhydrophobic coatings, this study co-deposited diamond micropowder into Ni-Cu composite coating using composite electrodeposition, followed by surface modification using 1H,1H,2H,2H-perfluorodecyltrimethoxysilane (PFDTES). Employing a variety of testing methods, this study investigated the impacts of the mass fractions of diamonds with particle sizes of 1 μm and 20 μm (also referred to as diamonds W1 and W20, respectively) on the surface morphology, roughness, superhydrophobicity, and superhydrophobic durability of the composite coatings. The chemical composition of the composite coatings was analyzed using energy-dispersive X-ray spectroscopy (EDS) and Fourier Transform Infrared (FTIR) spectroscopy, and erosion experiments on the coatings were carried out to explore their wear resistance. Results and Conclusions The results indicate that a high proportion of diamond W1 promoted the formation and evolution of cauliflower-like clusters, significantly enhancing the coatings’ superhydrophobicity. After fluorination modification of the coatings, the PFDTES molecules were successfully grafted onto their surfaces, effectively reducing their surface energy. The coatings containing only diamond W1 exhibited the optimal micro-nano hierarchical structure. These coatings delivered excellent superhydrophobic performance, with a contact angle reaching up to 159.3° ± 1.5° and a sliding angle of 0.5° ± 0.2°. The erosion experiments revealed that diamond W1 boosted the strength and hardness of cauliflower-like clusters, while diamond W20 protected the clusters (especially their sides) from direct wear by quartz sand. When the coatings contained 75% (mass fraction) diamond W1, diamonds with two particle sizes exhibited the optimal synergistic protection effects, with the coatings demonstrating excellent superhydrophobic durability and mud cake scaling resistance. The results of this study offer a practical solution to common issues encountered during drilling, such as drill bit balling and mud cake scaling on the internal walls of drilling tools, while also introducing new ideas for enhancing the durability of superhydrophobic coatings, thus holding significant potential for application.

Keywords

diamond, particle size, electrodeposition, superhydrophobicity, durability, Ni-Cu composite coating, surface modification of drilling tools

DOI

10.12363/issn.1001-1986.24.12.0815

Recommended Citation

WEN Qi, LI Tao, DUAN Longchen, et al. (2025) "Impacts of diamond particle sizes on performance of Ni-Cu superhydrophobic coatings on drilling tool surfaces," Coal Geology & Exploration: Vol. 53: Iss. 3, Article 21.
DOI: 10.12363/issn.1001-1986.24.12.0815
Available at: https://cge.researchcommons.org/journal/vol53/iss3/21

Reference

[1] 付孟雄，黄帅帅，刘少伟，等. 泥质软岩锚固孔钻渣泥化黏附特征及影响因素研究[J/OL]. 煤炭学报，2024：1–17 [2024-12-03]. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=MTXB20241115001&dbname=CJFD&dbcode=CJFQ.

FU Mengxiong，HUANG Shuaishuai，LIU Shaowei，et al. Characteristics of argillization and adhesion and influencing factors of drilling cuttings in borehole of roadway in soft argillaceous surrounding rock[J/OL]. Journal of China Coal Society，2024：1–17 [2024-12-03]. http://kns.cnki.net/KCMS/detail/detail.aspx?filename=MTXB20241115001&dbname=CJFD&dbcode=CJFQ.

[2] 杨冬冬，赵江鹏，赵建国. 水力反循环取芯技术在煤矿井下地质异常体探查中的应用[J]. 煤炭技术，2022，41(2)：72−75.

YANG Dongdong，ZHAO Jiangpeng，ZHAO Jianguo. Application of hydraulic reverse circulation coring technology in geologic anomaly exploration of coal mine[J]. Coal Technology，2022，41(2)：72−75.

[3] 姜政刚，张献振，高晓亮. 水敏性软硬交错地层瓦斯抽放孔PDC钻头的设计与应用[J]. 探矿工程(岩土钻掘工程)，2013，40(11)：49−51.

JIANG Zhenggang，ZHANG Xianzhen，GAO Xiaoliang. Design and application of PDC drill bit for gas drainage drilling in hard and soft water sensitive multi–inter–bedded formation[J]. Exploration Engineering(Rock & Soil Drilling and Tunneling)，2013，40(11)：49−51.

[4] 崔建. 不同类型钻头在大孔径瓦斯抽排井中的应用[J]. 能源与节能，2024(11)：210−212.

CUI Jian. Application of different types of drill bits in large–aperture gas extraction wells[J]. Energy and Energy Conservation，2024(11)：210−212.

[5] CAO Moyuan，GUO Dawei，YU Cunming，et al. Water–repellent properties of superhydrophobic and lubricant–infused “slippery” surfaces：A brief study on the functions and applications[J]. ACS Applied Materials & Interfaces，2016，8(6)：3615−3623.

[6] LIU Jianguo，FANG Xiuting，ZHU Chengyuan，et al. Fabrication of superhydrophobic coatings for corrosion protection by electrodeposition：A comprehensive review[J]. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2020，607：125498.

[7] DOU Renmei，CHEN Jing，ZHANG Yifan，et al. Anti–icing coating with an aqueous lubricating layer[J]. ACS Applied Materials & Interfaces，2014，6(10)：6998−7003.

[8] XIANG Yaolei，XUE Yahui，LYU Pengyu，et al. Influence of fluid flow on the stability and wetting transition of submerged superhydrophobic surfaces[J]. Soft Matter，2016，12(18)：4241−4246.

[9] 乔娟. WC–CoCr喷涂层织构化表面的疏水性与摩擦学性能[D]. 北京：中国地质大学(北京)，2018.

QIAO Juan. Hydrophobicity and tribological properties of WC–CoCr textured coatings prepared by HVOF spraying[D]. Beijing：China University of Geosciences (Beijing)，2018.

[10] 王睿哲. PTFE基复合涂层织构化表面的疏水性及耐磨性能[D]. 北京：中国地质大学(北京)，2020.

WANG Ruizhe. Hydrophobicity and wear resistance of textured surface of PTFE based composite coating[D]. Beijing：China University of Geosciences (Beijing)，2020.

[11] MARENYCH O，KOSTRYZHEV A. Strengthening mechanisms in nickel–copper alloys：A review[J]. Metals，2020，10(10)：1358.

[12] 潘军，王敏生，光新军. PDC钻头新进展及发展思考[J]. 石油机械，2016，44(11)：5−13.

PAN Jun，WANG Minsheng，GUANG Xinjun. New progress and future development of PDC bit[J]. China Petroleum Machinery，2016，44(11)：5−13.

[13] 贺旭，钟文辉. 石材加工用二次成型电镀薄壁钻头的研制[J]. 探矿工程(岩土钻掘工程)，1998，25(增刊1)：140−143.

HE Xu，ZHONG Wenhui. Development of the two–stage electro–plated thin kerf bit for dimension stone processing[J]. Exploration Engineering (Rock & Soil Drilling and Tunneling)，1998，25(Sup.1)：140−143.

[14] QUAN Yunyun，CHEN Zhong，LAI Yuekun，et al. Recent advances in fabricating durable superhydrophobic surfaces：A review in the aspects of structures and materials[J]. Materials Chemistry Frontiers，2021，5(4)：1655−1682.

[15] HUANG Jingda，LYU Shaoyi，CHEN Zhilin，et al. A facile method for fabricating robust cellulose nanocrystal/SiO₂ superhydrophobic coatings[J]. Journal of Colloid and Interface Science，2019，536：349−362.

[16] SALEHI M，MOZAMMEL M，EMARATI S M. Superhydrophobic and corrosion resistant properties of electrodeposited Ni–TiO₂/TMPSi nanocomposite coating[J]. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2019，573：196−204.

[17] DONG Shuhan，YANG Yang，LIANG Tingting，et al. Construction and corrosion resistance of Ni–B₄C superhydrophobic composite coatings on Q235 steel[J]. Surface and Coatings Technology，2021，422：127551.

[18] WANG Xin，WANG Bingbing，YANG Wei，et al. Fabrication of stable and versatile superhydrophobic PTFE coating by simple electrodeposition on metal surface[J]. Progress in Organic Coatings，2022，172：107090.

[19] ZHAO Guochen，XUE Yanpeng，HUANG Yuanfeng，et al. One–step electrodeposition of a self–cleaning and corrosion resistant Ni/WS₂ superhydrophobic surface[J]. RSC Advances，2016，6(64)：59104−59112.

[20] HONG Qiu，WANG Dingwen，YIN Shaohui. The microstructure，wear and electrochemical properties of electrodeposited Ni–diamond composite coatings：Effect of diamond concentration[J]. Materials Today Communications，2023，34：105476.

[21] YAZDANI S，MESBAH M，DUPONT V，et al. Microstructure，wear and crack propagation evolution of electrodeposited nickel–nano diamond composite coatings：Molecular dynamic modeling and experimental study[J]. Surface and Coatings Technology，2023，462：129500.

[22] 田佩佩. 复合电沉积制备油管超疏水表面工艺研究[D]. 淄博：山东理工大学，2021.

TIAN Peipei. Preparation of superhydrophobic surface of tubing by composite electrodeposition[D]. Zibo：Shandong University of Technology，2021.

[23] ZAHAVI J，HAZAN J. Electrodeposited nickel composites containing diamond particles[J]. Surface Technology White Papers，2023，110(4)：9−16.

[24] DAS M K，LI Rongxia，QIN Jiaqian，et al. Effect of electrodeposition conditions on structure and mechanical properties of Ni–W/diamond composite coatings[J]. Surface and Coatings Technology，2017，309：337−343.

[25] ANITHA C，AZIM S S，MAYAVAN S. Influence of particle size in fluorine free corrosion resistance superhydrophobic coating：Optimization and stabilization of interface by multiscale roughness[J]. Journal of Alloys and Compounds，2018，765：677−684.

[26] GONG Baichuan，MA Linjuan，GUAN Qian，et al. Preparation and particle size effects study of sustainable self–cleaning and durable silicon materials with superhydrophobic surface performance[J]. Journal of Environmental Chemical Engineering，2022，10(3)：107884.

[27] OGIHARA H，KATAYAMA T，SAJI T. One–step electrophoretic deposition for the preparation of superhydrophobic silica particle/trimethylsiloxysilicate composite coatings[J]. Journal of Colloid and Interface Science，2011，362(2)：560−566.

[28] SU Chengzhuang，ZHOU Lei，YUAN Chengyuan，et al. Robust superhydrophobic composite fabricated by a dual–sized particle design[J]. Composites Science and Technology，2023，231：109785.

[29] QIAO Gaoqun，WANG Shichao，WANG Xiaohu，et al. Preparation and corrosion protection performance of a pulse co–deposited Ni/Co/SiO₂ hydrophobic composite coating[J]. ChemPhysMater，2022，1(2)：119−125.

[30] HUANG Wei，ZHAO Yunwei，WANG Xiaolei. Preparing a high–particle–content Ni/diamond composite coating with strong abrasive ability[J]. Surface and Coatings Technology，2013，235：489−494.

[31] WENZEL R N. Resistance of solid surfaces to wetting by water[J]. Industrial & Engineering Chemistry，1936，28(8)：988−994.

[32] CASSIE A B D，BAXTER S. Wettability of porous surfaces[J]. Transactions of the Faraday Society，1944，40：546−551.

[33] QING Yongquan，HU Chuanbo，YANG Chuanning，et al. Rough structure of electrodeposition as a template for an ultrarobust self–cleaning surface[J]. ACS Applied Materials & Interfaces，2017，9(19)：16571−16580.

[34] YU Zhiqiang，ZHOU Chen，LIU Rong，et al. Fabrication of superhydrophobic surface with enhanced corrosion resistance on H62 brass substrate[J]. Colloids and Surfaces A：Physicochemical and Engineering Aspects，2020，589：124475.

[35] CHEN Sian，ZHU Benfeng，WANG Xuesheng，et al. Fabrication of superhydrophobic TA2 titanium alloy and preliminary assessment of its antifouling，self–cleaning，anti–icing，friction resistance，and corrosion resistance performance[J]. Journal of Coatings Technology and Research，2024，21(4)：1373−1383.

[36] KANG Chao，LU Houfang，YUAN Shaojun，et al. Superhydrophilicity/superhydrophobicity of nickel micro–arrays fabricated by electroless deposition on an etched porous aluminum template[J]. Chemical Engineering Journal，2012，203：1−8.

[37] SALEHIKAHRIZSANGI P，RAEISSI K，KARIMZADEH F，et al. Highly hydrophobic Ni–W electrodeposited film with hierarchical structure[J]. Surface and Coatings Technology，2018，344：626−635.

[38] KHORSAND S，RAEISSI K，ASHRAFIZADEH F，et al. Relationship between the structure and water repellency of nickel–cobalt alloy coatings prepared by electrodeposition process[J]. Surface and Coatings Technology，2015，276：296−304.

[39] KHORSAND S，RAEISSI K，ASHRAFIZADEH F. Corrosion resistance and long–term durability of super–hydrophobic nickel film prepared by electrodeposition process[J]. Applied Surface Science，2014，305：498−505.

[40] XUE Yanpeng，WANG Shuqiang，BI Peng，et al. Super–hydrophobic co–Ni coating with high abrasion resistance prepared by electrodeposition[J]. Coatings，2019，9(4)：232.

[41] SHEN Lida，FAN Mingzhi，QIU Mingbo，et al. Superhydrophobic nickel coating fabricated by scanning electrodeposition[J]. Applied Surface Science，2019，483：706−712.

[42] YAO Kaili，DAI Bing，MAY P W，et al. Hydrophobicity and adhesion of aggregated diamond particles[J]. Physica Status Solidi A：Applications and Materials Science，2021，218(5)：2000355.

[43] MAZUREK A，TRZASKA M. Structure and properties of Ni/diamond nanocrystalline coatings[J]. Archives of Metallurgy and Materials，2019，64(4)：1309−1314.