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Coal Geology & Exploration

Abstract

Background The coal gangue, a solid waste, features high production and a continuous increase in the amount piled in China. The long-term piling up of coal gangue will cause the waste of land resources and environmental pollution in mining areas. Various methods for utilizing coal gangue, such as preparing high-value-added chemical products and extracting useful elements, suffer a limited consumption capacity, failing to meet the requirements of large-scale disposal and utilization of solid wastes and green mine construction. Advances The comprehensive utilization of coal gangue for mining area reclamation and underground backfilling represents a critical direction for its large-scale disposal and utilization. This study systematically summarizes the physicochemical properties and resource attributes of coal gangue and analyzes the impacts of its long-term piling up on the atmosphere, soils, and water in mining areas. From the perspective of green mine construction, this study highlights the principles, advances, and application effects of technologies for large-scale disposal and utilization of coal gangue. These technologies include the utilization of coal gangue as materials for the reclamation of collapse areas, geopolymer grouting materials, solid filling materials, paste filling materials, and paste-like filling materials. The results reveal that when used as materials for reclamation, coal gangue can improve soil properties and promote plant growth, yet it poses challenges of short-term heavy metal migration and environmental contamination. When used as geopolymer grouting materials, coal gangue can effectively immobilize heavy metals within it, suppressing their release and reducing their damage to the environment. The solid backfilling technology tailored to coal gangue enjoys advantages including simple coal gangue processing technique and minimal consumption of auxiliary materials. However, this technology faces challenges like uneven filling and groundwater contamination. Furthermore, this study summarizes the composition and flowability advantages of coal gangue when used as paste and paste-like filling materials and analyzes its microscopic hydration mechanisms and flow properties, providing key technical support for backfill mining of mines. Finally, this study points out some issues concerning the utilization of coal gangue, including challenges in the full stimulation and utilization of the activity of coal gangue, the absence of classification and pretreatment in the early stage, high cost of utilization as underground backfilling and grouting materials, and a lack of incentive policies for large-scale utilization. Prospects To promote the large-scale utilization of coal gangue in mining areas in a safe, efficient, and risk-controllable manner, future research will focus on the cost-effective composite activation methods, environmental friendliness assessment of utilization processes, CO2 mineralization and sequestration, and carbon-negative utilization of coal gangue. These efforts will provide insights for the comprehensive utilization of coal gangue following the "green-efficient-high value" roadmap, expand the large-scale utilization of coal gangue, and enhance the risk prevention abilities in this regard, thus promoting the synergetic development of solid waste utilization and green mine construction.

Keywords

green mine, coal gangue, solid waste utilization, reclamation, filling, activation, carbon-negative

DOI

10.12363/issn.1001-1986.24.09.0590

Reference

[1] 徐燕飞,陈永春,李静,等. 煤电基地CO2和CH4遥感监测及时空特征分析[J]. 煤田地质与勘探,2024,52(6):79−90.

XU Yanfei,CHEN Yongchun,LI Jing,et al. Remote sensing monitoring and spatiotemporal characteristics of CO2 and CH4 concentrations in coal–electricity production bases[J]. Coal Geology & Exploration,2024,52(6):79−90.

[2] LIU Yin,WEN Hu,CHEN Changming,et al. Research status and development trend of coal spontaneous combustion fire and prevention technology in China:A review[J]. ACS Omega,2024,9(20):21727−21750.

[3] 李华焜,郑刘根,陈永春,等. 基于CT扫描的重构土壤孔隙结构及其对水盐运移影响[J]. 煤田地质与勘探,2024,52(4):120−127.

LI Huakun,ZHENG Liugen,CHEN Yongchun,et al. Exploring the pore structure of reconstructed soils and its effects on water and salt transport based on CT scanning[J]. Coal Geology & Exploration,2024,52(4):120−127.

[4] CAO Yachuan,ZHOU Chuncai,GAO Feiyue,et al. Lithium recovery from typical coal–based solid wastes:Critical technologies,challenges,and prospects[J]. Chemical Engineering Journal,2024,498:155121.

[5] 朱琦,胡振琪,叶春,等. 基于化学–微生物法的煤矸石山酸化污染原位控制技术研究进展[J]. 中国矿业,2023,32(1):52−59.

ZHU Qi,HU Zhenqi,YE Chun,et al. Research progress of in situ control technology for acidification pollution of coal gangue pile based on chemical–microbial method[J]. China Mining Magazine,2023,32(1):52−59.

[6] WANG Haiyan,TAN Bo,ZHANG Xuedong. Research on the technology of detection and risk assessment of fire areas in gangue hills[J]. Environmental Science and Pollution Research,2020,27(31):38776−38787.

[7] PAN Rongkun,ZHENG Ligang,JIA H,et al. The environmental pollution and control of coal gangue spontaneous combustion in mining[J]. Electronic Journal of Geotechnical Engineering,2015,20(8):3555−3562.

[8] 李振,雪佳,朱张磊,等. 煤矸石综合利用研究进展[J]. 矿产保护与利用,2021,41(6):165−178.

LI Zhen,XUE Jia,ZHU Zhanglei,et al. Research progress on comprehensive utilization of coal gangue[J]. Conservation and Utilization of Mineral Resources,2021,41(6):165−178.

[9] 王艳,左震,文波,等. 煤矸石粗集料理化性质和形状特征对混凝土强度的影响[J]. 矿业科学学报,2022,7(5):554−564.

WANG Yan,ZUO Zhen,WEN Bo,et al. Influence of physicochemical properties and shape characteristics of coal gangue coarse aggregate on concrete strength[J]. Journal of Mining Science and Technology,2022,7(5):554−564.

[10] 姚苏琴,查文华,刘新权,等. 萍乡废弃煤矸石理化特性及热活化性能研究[J]. 硅酸盐通报,2021,40(7):2280−2287.

YAO Suqin,ZHA Wenhua,LIU Xinquan,et al. Physicochemical and thermal activation properties of waste coal gangue in Pingxiang mining area[J]. Bulletin of the Chinese Ceramic Society,2021,40(7):2280−2287.

[11] 包宏亮. 山西西铭矿煤矸石基础性质及资源化利用研究[J]. 中国煤炭地质,2021,33(10):121−124.

BAO Hongliang. Study on coal gangue fundamental natures and reutilization in Ximing coalmine,Shanxi[J]. Coal Geology of China,2021,33(10):121−124.

[12] MA Hongqiang,WU Chao. Feasibility and performance evaluation of cementitious material mixed with coal gangue solid waste[M]//QI Chongchong,BENSON C H. Managing mining and minerals processing wastes. Amsterdam:Elsevier,2023:99–130.

[13] 庄红峰. 制砖物料中黏土矿物成分含量对烧结砖的影响[J]. 砖瓦,2020(2):46−49.

ZHUANG Hongfeng. Effect of clay mineral content in brick making materials on fired brick[J]. Brick–Tile,2020(2):46−49.

[14] 贾建慧,马宁,董阳,等. 煤矸石综合利用研究进展[J]. 洁净煤技术,2024,30(增刊1):36−45.

JIA Jianhui,MA Ning,DONG Yang,et al. Review on the comprehensive utilization of coal gangue[J]. Clean Coal Technology,2024,30(Sup.1):36−45.

[15] 胡振琪,肖武. 关于煤炭工业绿色发展战略的若干思考:基于生态修复视角[J]. 煤炭科学技术,2020,48(4):35−42.

HU Zhenqi,XIAO Wu. Some thoughts on green development strategy of coal industry:From aspects of ecological restoration[J]. Coal Science and Technology,2020,48(4):35−42.

[16] 王金满,杨曼,刘彪,等. 绿色矿山建设碳源/汇与减排增汇研究进展[J]. 煤炭学报,2024,49(3):1597−1610.

WANG Jinman,YANG Man,LIU Biao,et al. Carbon sources/sinks and emission reduction and sink enhancement in green mining[J]. Journal of China Coal Society,2024,49(3):1597−1610.

[17] 刘萍,晏飞. 煤矸石对环境的危害及其综合治理[J]. 中国矿业,2008,17(8):49−51.

LIU Ping,YAN Fei. Coal rock harmful to the environment and comprehensive management[J]. China Mining Magazine,2008,17(8):49−51.

[18] 于水军,余明高,段玉龙,等. 自燃煤矸石山爆炸的热力学模拟[J]. 煤炭学报,2007,32(9):945−949.

YU Shuijun,YU Minggao,DUAN Yulong,et al. Thermodynamic simulation of explosion of self–combustion gangue heap[J]. Journal of China Coal Society,2007,32(9):945−949.

[19] 刘迪. 煤矸石的环境危害及综合利用研究[J]. 气象与环境学报,2006,22(3):60−62.

LIU Di. Research on environmental effect and comprehensive utilization of coal–waste rocks[J]. Journal of Meteorology and Environment,2006,22(3):60−62.

[20] LI Yuanyuan,CAO Yingjia,RUAN Mengying,et al. Mechanism and in situ prevention of oxidation in coal gangue piles:A review aiming to reduce acid pollution[J]. Sustainability,2024,16(16):7208.

[21] DONG Yingbo,LU Huan,LIN Hai. Comprehensive study on the spatial distribution of heavy metals and their environmental risks in high–sulfur coal gangue dumps in China[J]. Journal of Environmental Sciences,2024,136:486−497.

[22] 秦建良. 煤矸石的危害及综合利用现状[J]. 广州化工,2015,43(4):25−27.

QIN Jianliang. The harm of coal gangue and the present situation of comprehensive utilization[J]. Guangzhou Chemical Industry,2015,43(4):25−27.

[23] 雷建红. 煤矸石的污染危害与综合利用分析[J]. 能源与节能,2017(4):90−91.

LEI Jianhong. Analysis of pollution hazards and comprehensive utilization of coal gangue[J]. Energy and Energy Conservation,2017(4):90−91.

[24] GAO Huadong,HUANG Yanli,LI Wei,et al. Explanation of heavy metal pollution in coal mines of China from the perspective of coal gangue geochemical characteristics[J]. Environmental Science and Pollution Research,2021,28(46):65363−65373.

[25] 孔涛,张开,黄丽华,等. 菌剂混施对各粒径矸石性质及苜蓿生长的影响[J]. 煤炭学报,2023,48(增刊1):241−251

KONG Tao,ZHANG Kai,HUANG Lihua,et al. Effects of mixed application of microbial agents on growth and substrate properties of alfalfa in coal gangue matrix with different particle sizes[J]. Journal of China Coal Society,2023,48(Sup.1):241−251.

[26] 周昊,郭娇娇,何绪文,等. 煤矿区固废改良土壤对植物生长的影响[J]. 煤炭技术,2018,37(3):23−25.

ZHOU Hao,GUO Jiaojiao,HE Xuwen,et al. Research on impact of coal solid waste improved soil on plant growth[J]. Coal Technology,2018,37(3):23−25.

[27] ZHANG Kun,XU Liangji,HUANG Guodong,et al. Coupled variations of soil temperature and moisture in reclaimed fields filled with coal gangue of different grain size distributions[J]. Journal of Soils and Sediments,2020,20(4):2248−2259.

[28] 郭友红,李树志,鲁叶江. 塌陷区矸石充填复垦耕地覆土厚度的研究[J]. 矿山测量,2008,36(2):59−61.

GUO Youhong,LI Shuzhi,LU Yejiang. Research on depth of the covering layer on reclaimed cultivated land backfilled with coal refuse in subsidence area[J]. Mine Surveying,2008,36(2):59−61.

[29] 胡振琪,康惊涛,魏秀菊,等. 煤基混合物对复垦土壤的改良及苜蓿增产效果[J]. 农业工程学报,2007,23(11):120−124.

HU Zhenqi,KANG Jingtao,WEI Xiuju,et al. Experimental research on improvement of reclaimed soil properties and plant production based on different ratioes of coal–based mixed materials[J]. Transactions of the Chinese Society of Agricultural Engineering,2007,23(11):120−124.

[30] DU Tao,WANG Dongmei,BAI Yujie,et al. Optimizing the formulation of coal gangue planting substrate using wastes:The sustainability of coal mine ecological restoration[J]. Ecological Engineering,2020,143:105669.

[31] TANG Quan,LI Liyuan,ZHANG Song,et al. Characterization of heavy metals in coal gangue–reclaimed soils from a coal mining area[J]. Journal of Geochemical Exploration,2018,186:1−11.

[32] 冯印成,赵康,田向勤,等. 煤矸石回填塌陷区重金属淋溶迁移时空规律研究[J/OL]. 中国环境科学,2024:1–12 [2025-02-27]. https://doi.org/10.19674/j.cnki.issn1000–6923.20241104.002.

FENG Yincheng,ZHAO Kang,TIAN Xiangqin,et al. Research on spatiotemporal patterns of heavy metal leaching and migration in coal gangue backfill subsidence area[J/OL]. China Environmental Science,2024:1–12 [2025-02-27]. https://doi.org/10.19674/j.cnki.issn1000–6923.20241104.002.

[33] LI Fang,LI Xinju,HOU Le,et al. A long–term study on the soil reconstruction process of reclaimed land by coal gangue filling[J]. CATENA,2020,195:104874.

[34] 毕银丽,吴王燕,刘银平. 丛枝菌根在煤矸石山土地复垦中的应用[J]. 生态学报,2007,27(9):3738−3743.

BI Yinli,WU Wangyan,LIU Yinping. Application of arbuscular mycorrhizas in land reclamation of coal spoil heaps[J]. Acta Ecologica Sinica,2007,27(9):3738−3743.

[35] 刘帆俞,宋慧平,吴海滨,等. 煤矸石土壤化利用与土壤改良剂研究进展[J]. 矿产保护与利用,2023,43(6):14−26.

LIU Fanyu,SONG Huiping,WU Haibin,et al. Research progress on the utilization of coal gangue for soil remediation and as soil amendment agents[J]. Conservation and Utilization of Mineral Resources,2023,43(6):14−26.

[36] HAN Ruicong,GUO Xiaoning,GUAN Junfeng,et al. Activation mechanism of coal gangue and its impact on the properties of geopolymers:A review[J]. Polymers,2022,14(18):3861.

[37] QIAN Lanping,XU Lingyu,ALREFAEI Y,et al. Artificial alkali–activated aggregates developed from wastes and by–products:A state–of–the–art review[J]. Resources,Conservation and Recycling,2022,177:105971.

[38] GUAN Xiao,CHEN Jixi,ZHU Mengyu,et al. Performance of microwave–activated coal gangue powder as auxiliary cementitious material[J]. Journal of Materials Research and Technology,2021,14:2799−2811.

[39] LIU Yi,YAN Chunjie,ZHANG Zuhua,et al. A comparative study on fly ash,geopolymer and faujasite block for Pb removal from aqueous solution[J]. Fuel,2016,185:181−189.

[40] ZHANG Benfeng,YANG Kang,ZHANG Kai,et al. Migration transformation,prevention,and control of typical heavy metal lead in coal gangue:A review[J]. International Journal of Coal Science & Technology,2023,10(1):85.

[41] 郭凌志,周梅,王丽娟,等. 煤基固废地聚物注浆材料的制备及性能[J]. 建筑材料学报,2022,25(10):1092−1100.

GUO Lingzhi,ZHOU Mei,WANG Lijuan,et al. Preparation and properties of coal–based solid waste geopolymer grouting materials[J]. Journal of Building Materials,2022,25(10):1092−1100.

[42] PANG Shuai,ZHANG Xiangdong,ZHU Kaixin,et al. Study on mechanical properties and micro characterization of fibre reinforced ecological cementitious coal gangue materials[J]. Polymers,2023,15(3):700.

[43] HUANG Guodong,JI Yongsheng,LI Jun,et al. Improving strength of calcinated coal gangue geopolymer mortars via increasing calcium content[J]. Construction and Building Materials,2018,166:760−768.

[44] GUO Lingzhi,LIU Juanhong,ZHOU Mei,et al. Effect of an alkali activators on the compressive strength and reaction mechanism of coal gangue–slag–fly ash geopolymer grouting materials[J]. Construction and Building Materials,2024,426:136012.

[45] ZHANG Weiqing,DONG Chaowei,HUANG Peng,et al. Experimental study on the characteristics of activated coal gangue and coal gangue–based geopolymer[J]. Energies,2020,13(10):2504.

[46] WANG Qingping,ZHU Longtao,LU Chunyang,et al. Investigation on the effect of calcium on the properties of geopolymer prepared from uncalcined coal gangue[J]. Polymers,2023,15(5):1241.

[47] 徐法奎. 我国煤矿充填开采现状及发展前景[J]. 煤矿开采,2012,17(4):6−7.

XU Fakui. Current status of stowing mining and its development prospect in China[J]. Coal Mining Technology,2012,17(4):6−7.

[48] LI Junmeng,HUANG Yanli,CHEN Zhongwei,et al. Characterizations of macroscopic deformation and particle crushing of crushed gangue particle material under cyclic loading:In solid backfilling coal mining[J]. Powder Technology,2019,343:159−169.

[49] 刘建功,王英. 固体充填材料比例特征及应力特性研究[J]. 中国煤炭,2017,43(5):38−42.

LIU Jiangong,WANG Ying. Research on ratio characteristics and stress properties of solid filling materials[J]. China Coal,2017,43(5):38−42.

[50] 闫善飞,史艳楠,王翰秋,等. 固体充填胶凝材料试验研究与应用[J]. 煤炭工程,2022,54(3):143−147.

YAN Shanfei,SHI Yannan,WANG Hanqiu,et al. Experimental research and application of solid filling cementitious materials[J]. Coal Engineering,2022,54(3):143−147.

[51] JU Feng,LI Baiyi,GUO Shuai,et al. Dynamic characteristics of gangues during vertical feeding in solid backfill mining:A case study of the Wugou Coal Mine in China[J]. Environmental Earth Sciences,2016,75(20):1389.

[52] 孔国强,宋天奇,李俊孟. 松散矸石压缩特性的尺寸效应数值模拟[J]. 煤炭技术,2017,36(7):69−71.

KONG Guoqiang,SONG Tianqi,LI Junmeng. Size effect of compression feature of loose gangue by numerical simulation[J]. Coal Technology,2017,36(7):69−71.

[53] LI Meng,LI Ailing,ZHANG Jixiong,et al. Effects of particle sizes on compressive deformation and particle breakage of gangue used for coal mine goaf backfill[J]. Powder Technology,2020,360:493−502.

[54] 何泽全,巨峰,肖猛,等. 煤矸石充填材料在循环载荷作用下的细观变形特征分析[J]. 采矿与安全工程学报,2022,39(5):1002−1010.

HE Zequan,JU Feng,XIAO Meng,et al. Characterization of meso–deformation of gangue backfilling materials under cyclic loading[J]. Journal of Mining & Safety Engineering,2022,39(5):1002−1010.

[55] 李晓彤. 水–力耦合淋溶作用下煤矸石重金属析出释放规律研究[D]. 徐州:中国矿业大学,2023.

LI Xiaotong. Characterization of heavy metal releasing from coal gangue under water–force coupled leaching[D]. Xuzhou:China University of Mining and Technology,2023.

[56] 张云,刘永孜,来兴平,等. 基于导水裂隙扩展–重金属离子迁移的短壁块段式充填保水采煤机理研究[J]. 煤炭科学技术,2023,51(2):155−172.

ZHANG Yun,LIU Yongzi,LAI Xingping,et al. Mechanism of short–wall block backfill water–preserved mining based on water–conducting fractures development–heavy metal ions migration[J]. Coal Science and Technology,2023,51(2):155−172.

[57] 刘文生,张燕凤,张贺然. 膏体充填材料的工作特性及强度特性研究[J]. 硅酸盐通报,2015,34(4):1116−1120.

LIU Wensheng,ZHANG Yanfeng,ZHANG Heran. Study on the working and strength characteristics of paste filling material[J]. Bulletin of the Chinese Ceramic Society,2015,34(4):1116−1120.

[58] 刘音,李金平,路瑶,等. 煤矸石大粒径粗骨料比例对充填膏体性能影响的试验研究[J]. 煤矿开采,2016,21(5):1−3.

LIU Yin,LI Jinping,LU Yao,et al. Experimental studying of coal gangue large particle size coarse aggregate ratio to filling paste property[J]. Coal Mining Technology,2016,21(5):1−3.

[59] CHEN Shaojie,DU Zhaowen,ZHANG Zhen,et al. Effects of chloride on the early mechanical properties and microstructure of gangue–cemented paste backfill[J]. Construction and Building Materials,2020,235:117504.

[60] 陈瑞毅. 煤基固废膏体充填材料力学特性实验研究[D]. 淮南:安徽理工大学,2022.

CHEN Ruiyi. Experimental study on mechanical properties of coal based solid waste paste filling material[D]. Huainan:Anhui University of Science and Technology,2022.

[61] SUN Qi,WEI Xueda,WEN Zhijie. Preparation and strength formation mechanism of surface paste disposal materials in coal mine collapse pits[J]. Journal of Materials Research and Technology,2022,17:1221−1231.

[62] ZHANG Leiming,LAI Xingping,PAN Jiliang,et al. Experimental investigation on the mixture optimization and failure mechanism of cemented backfill with coal gangue and fly ash[J]. Powder Technology,2024,440:119751.

[63] ZHANG Xinguo,LIN Jia,LIU Jinxiao,et al. Investigation of hydraulic–mechanical properties of paste backfill containing coal gangue–fly ash and its application in an underground coal mine[J]. Energies,2017,10(9):1309.

[64] 牛丽菊,郑帅亮. 煤矿膏体充填对地下水环境影响研究[J]. 煤,2024,33(3):100−104.

[65] ZHANG Feng,LIU Jinxiao,NI Haiming,et al. Development of coal mine filling paste with certain early strength and its flow characteristics[J]. Geofluids,2021,2021(1):6699426.

[66] 王新民,龚正国,张传恕,等. 似膏体自流充填工艺在孙村煤矿的应用[J]. 矿业研究与开发,2008,28(2):10−13.

WANG Xinmin,GONG Zhengguo,ZHANG Chuanshu,et al. Application of gravity–flowed paste–like slurry filling technology in Suncun Coal Mine[J]. Mining Research and Development,2008,28(2):10−13.

[67] 王新民,曹刚,龚正国. 煤矸石作充填骨料的似膏体料浆流动性能试验研究[J]. 矿业快报,2008,24(1):20−23.

WANG Xinmin,CAO Gang,GONG Zhengguo. Experimental research on flow performance of paste–like slurry with gangue as filling aggregate[J]. Express Information of Mining Industry,2008,24(1):20−23.

[68] 刘晓玲,王新民,吴鹏. 煤矸石似膏体快速充填试验研究[J]. 金属矿山,2011(6):6−8.

LIU Xiaoling,WANG Xinmin,WU Peng. Experimental research of rapid filling with paste–like coal gangue[J]. Metal Mine,2011(6):6−8.

[69] 顾清恒. 似膏体充填材料配比的BP网络优化方法[J]. 金属矿山,2016(3):40−43.

GU Qingheng. Mixing proportion of paste–like filling material based on back–propagation neural network[J]. Metal Mine,2016(3):40−43.

[70] 郝宇鑫,黄玉诚,李育松,等. 矸石似膏体充填料浆临界流速影响因素研究[J]. 煤炭工程,2022,54(4):128−133.

HAO Yuxin,HUANG Yucheng,LI Yusong,et al. Influencing factors of critical flow rate of gangue paste–like filler slurry[J]. Coal Engineering,2022,54(4):128−133.

[71] 张钦礼,谢盛青,郑晶晶,等. 充填料浆沉降规律研究及输送可行性分析[J]. 重庆大学学报,2011,34(1):105−109.

ZHANG Qinli,XIE Shengqing,ZHENG Jingjing,et al. Sedimentation law research and transportation feasibility study of backfilling slurry[J]. Journal of Chongqing University,2011,34(1):105−109.

[72] 赵卫强,吕艳奎,黄玉诚. 似膏体料浆管输中浆击分析与计算研究[J]. 煤炭工程,2015,47(8):96−98.

ZHAO Weiqiang,LYU Yankui,HUANG Yucheng. Analysis and calculation of slurry water–hammer in paste–like slurry pipeline transport[J]. Coal Engineering,2015,47(8):96−98.

[73] 曹小刚. 新型骨料似膏体胶结充填技术研究[D]. 长沙:中南大学,2012.

CAO Xiaogang. Study on new aggregate paste–like backfilling technology[D]. Changsha:Central South University,2012.

[74] 姚志全,张钦礼,王新民. 减水剂在似膏体胶结充填中的应用[J]. 煤矿安全,2009,40(1):43−45

[75] 崔增娣,孙恒虎. 煤矸石凝石似膏体充填材料的制备及其性能[J]. 煤炭学报,2010,35(6):896−899.

CUI Zengdi,SUN Henghu. The preparation and properties of coal gangue based sialite paste–like backfill material[J]. Journal of China Coal Society,2010,35(6):896−899.

[76] 王莹莹,谢光天,李泽荃. 煤矸石质似膏体充填胶结料的研制及水化机理研究[J]. 煤炭工程,2017,49(12):141−144.

WANG Yingying,XIE Guangtian,LI Zequan. Research on coal gangue paste–like filling materials and its hydration mechanism[J]. Coal Engineering,2017,49(12):141−144.

[77] 张云,刘永孜,曹胜根,等. 短壁块段式充填采煤矸石充填材料重金属离子“下行”迁移规律及控制技术[J]. 采矿与安全工程学报,2023,40(2):284−294.

ZHANG Yun,LIU Yongzi,CAO Shenggen,et al. Study on the migration law and control of heavy metal ions “downward” in gangue backfill materials in short–wall block backfill mining[J]. Journal of Mining & Safety Engineering,2023,40(2):284−294.

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