Links of intensification chemical weathering and nickel enrichment with volcanism in the North China Plate around the Permian-Triassic Boundary

Authors

WANG Ye, School of Civil Engineering, Shenyang Jianzhu University, Shenyang 110168, ChinaFollow
YE Chengzhuo, School of Civil Engineering, Shenyang Jianzhu University, Shenyang 110168, China
ZHANG Tong, CCTEG Xi’an Research Institute (Group) Co., Ltd., Xi’an 710077, China
YANG Minfang, Research Institute of Petroleum Exploration and Development Research Institute, PetroChina, Beijing 100083, China
ZHOU Kai, State Key Laboratory for Fine Exploration and Intelligent Development of Coal Resources, China University of Mining and Technology (Beijing), Beijing 100083, China
ZHANG Peixin, Henan International Joint Laboratory for Green Low Carbon-Water Treatment Technology and Water Resources Utilization, School of Municipal and Environmental Engineering, Henan University of Urban Construction, Pingdingshan 467036, China
YANG Yuzhu, School of Civil Engineering, Shenyang Jianzhu University, Shenyang 110168, China
ZHANG Chu, School of Civil Engineering, Shenyang Jianzhu University, Shenyang 110168, China
LU Jing, State Key Laboratory for Fine Exploration and Intelligent Development of Coal Resources, China University of Mining and Technology (Beijing), Beijing 100083, ChinaFollow

Abstract

Objective The North China Plate serves as a pivotal region for deciphering the mechanisms underlying the links of volcanism and paleoenvironmental-climatic upheavals around the Permian-Triassic Boundary (PTB). The dramatic environmental perturbations during this period are closely linked to large-scale volcanic eruptions of the Siberian Traps Large Igneous Province (STLIP). These eruptions triggered global warming, extreme chemical weathering events, and mass extinctions, marking a significant turning point in the evolution of the Earth system.Methods This study investigated the Sunjiagou and Liujiagou formations in the WY-U-01H borehole in the Qinshui Basin, North China Plate. Using the chemical index of alteration (CIA), combined with geochemical tracers such as the nickel (Ni) concentration and Ni/Al ratio, this study compared the chemical weathering intensity and abnormal Ni enrichment in the North China Plate around the PTB. Accordingly, it explored the links of their evolution with the contemporaneous atmospheric CO₂ concentrations, volcanism, and mass extinction event.Results and Conclusions The results reveal that the study area keeps a record of an intensified continental weathering episode around the PTB, aligning with observations from multiple sections in the North China Plate. Ni enrichment anomalies are concentrated near the PTB horizon, marking the STLIP emplacement. It is considered that the STLIP induced climate warming by releasing greenhouse gas, thereby resulting in intensified global continental weathering. Meanwhile, the concurrent terrestrial plant extinctions caused by wildfires destroyed surface ecological barriers and biogeochemical cycles, further intensifying continental weathering. The results of this study provide critical evidence for revealing the paleoclimatic responses and ecological feedback of the North China Plate to the PTB events, deepening the understanding of the global environmental effect of the STLIP volcanism.

Keywords

North China Plate, Permian-Triassic Boundary (PTB), chemical weathering, abnormal nickel (Ni) enrichment

DOI

10.12363/issn.1001-1986.25.05.0346

Recommended Citation

WANG Ye, YE Chengzhuo, ZHANG Tong, et al. (2025) "Links of intensification chemical weathering and nickel enrichment with volcanism in the North China Plate around the Permian-Triassic Boundary," Coal Geology & Exploration: Vol. 53: Iss. 10, Article 34.
DOI: 10.12363/issn.1001-1986.25.05.0346
Available at: https://cge.researchcommons.org/journal/vol53/iss10/34

Reference

[1] ERWIN D H. The Permo–Triassic extinction[J]. Nature，1994，367(6460)：231−236.

[2] BENTON M J，NEWELL A J. Impacts of global warming on Permo–Triassic terrestrial ecosystems[J]. Gondwana Research，2014，25(4)：1308−1337.

[3] BURGESS S D，BOWRING S，SHEN Shuzhong. High–precision timeline for Earth’s most severe extinction[J]. Proceedings of the National Academy of Sciences of the United States of America，2014，111(9)：3316−3321.

[4] BURGESS S D，BOWRING S A. High–precision geochronology confirms voluminous magmatism before，during，and after Earth’s most severe extinction[J]. Science Advances，2015，1(7)：e1500470.

[5] YIN Hongfu，FENG Qinglai，LAI Xulong，et al. The protracted Permo–Triassic crisis and multi–episode extinction around the Permian–Triassic boundary[J]. Global and Planetary Change，2007，55(1/2/3)：1−20.

[6] CUI Ying，LI Mingsong，VAN SOELEN E E，et al. Massive and rapid predominantly volcanic CO₂ emission during the end–Permian mass extinction[J]. Proceedings of the National Academy of Sciences of the United States of America，2021，118(37)：e2014701118.

[7] ALGEO T J. Anomalous Early Triassic sediment fluxes due to elevated weathering rates[J]. Journal of Earth Science，2010，21：107−110.

[8] SHEN Shuzhong，CROWLEY J L，WANG Yue，et al. Calibrating the end–Permian mass extinction[J]. Science，2011，334(6061)：1367−1372.

[9] BOND D P G，GRASBY S E. On the causes of mass extinctions[J]. Palaeogeography，Palaeoclimatology，Palaeoecology，2017，478：3−29.

[10] SHEN Shuzhong，CAO Changqun，ZHANG Hua，et al. High–resolution δ¹³C_carb chemostratigraphy from latest Guadalupian through earliest Triassic in South China and Iran[J]. Earth and Planetary Science Letters，2013，375：156−165.

[11] ZHANG Peixin，YANG Minfang，LU Jing，et al. End–Permian terrestrial ecosystem collapse in North China：Evidence from palynology and geochemistry[J]. Global and Planetary Change，2023，222：104070.

[12] FIELDING C R，FRANK T D，MCLOUGHLIN S，et al. Age and pattern of the southern high–latitude continental end–Permian extinction constrained by multiproxy analysis[J]. Nature Communications，2019，10：385.

[13] MAYS C，MCLOUGHLIN S，FRANK T D，et al. Lethal microbial blooms delayed freshwater ecosystem recovery following the end–Permian extinction[J]. Nature Communications，2021，12：5511.

[14] XU Zhen，HILTON J，YU Jianxin，et al. End Permian to Middle Triassic plant species richness and abundance patterns in South China：Coevolution of plants and the environment through the Permian–Triassic transition[J]. Earth–Science Reviews，2022，232：104136.

[15] WARD P D，MONTGOMERY D R，SMITH R. Altered river morphology in South Africa related to the Permian–Triassic extinction[J]. Science，2000，289(5485)：1740−1743.

[16] LU Jing，WANG Ye，YANG Minfang，et al. Diachronous end–Permian terrestrial ecosystem collapse with its origin in wildfires[J]. Palaeogeography，Palaeoclimatology，Palaeoecology，2022，594：110960.

[17] LU Jing，ZHANG Peixin，YANG Minfang，et al. Continental records of organic carbon isotopic composition (δ¹³C_org)，weathering，paleoclimate and wildfire linked to the end–Permian mass extinction[J]. Chemical Geology，2020，558：119764.

[18] BUGGLE B，GLASER B，HAMBACH U，et al. An evaluation of geochemical weathering indices in loess–paleosol studies[J]. Quaternary International，2011，240(1)：12−21.

[19] 尚冠雄. 华北地台晚古生代煤地质学研究[M]. 太原：山西科学技术出版社，1997.

[20] CAO Ying，SONG Huyue，ALGEO T J，et al. Intensified chemical weathering during the Permian–Triassic transition recorded in terrestrial and marine successions[J]. Palaeogeography，Palaeoclimatology，Palaeoecology，2019，519：166−177.

[21] SHAO Longyi，YANG Zhiyu，SHANG Xiaoxu，et al. Lithofacies palaeogeography of the Carboniferous and Permian in the Qinshui Basin，Shanxi Province，China[J]. Journal of Palaeogeography (English)，2015，4(4)：384−412.

[22] WANG Jun. Late Paleozoic macrofloral assemblages from Weibei Coalfield，with reference to vegetational change through the Late Paleozoic Ice–age in the North China Block[J]. International Journal of Coal Geology，2010，83(2/3)：292−317.

[23] 舒文超. 二叠纪–三叠纪陆地植物群演变：来自华北、华南和新疆地区的化石证据[D]. 武汉：中国地质大学，2022.

SHU Wenchao. Permian–Triassic floral successions：Fossil evidence from North China，South China and Xinjiang[D]. Wuhan：China University of Geosciences，2022.

[24] 邵龙义，张天畅. 泥质岩定义及分类问题的探讨[J]. 古地理学报，2023，25(4)：742−751.

SHAO Longyi，ZHANG Tianchang. Discussion on definition and classification of mudrock[J]. Journal of Palaeogeography (Chinese Edition)，2023，25(4)：742−751.

[25] CHU Daoliang，GRASBY S E，SONG Haijun，et al. Ecological disturbance in tropical peatlands prior to marine Permian–Triassic mass extinction[J]. Geology，2020，48(3)：288−292.

[26] LU Jing，WANG Ye，YANG Minfang，et al. Records of volcanism and organic carbon isotopic composition (δ¹³C_org) linked to changes in atmospheric pCO₂ and climate during the Pennsylvanian icehouse interval[J]. Chemical Geology，2021，570：120168.

[27] MCLENNAN S M. Weathering and global denudation[J]. The Journal of Geology，1993，101：295−303.

[28] NESBITT H W，YOUNG G M. Early Proterozoic climates and plate motions inferred from major element chemistry of lutites[J]. Nature，1982，299(5885)：715−717.

[29] FEDO C M，NESBITT H W，YOUNG G M. Unraveling the effects of potassium metasomatism in sedimentary rocks and paleosols，with implications for paleoweathering conditions and provenance[J]. Geology，1995，23(10)：921−924.

[30] GARZANTI E，PADOAN M，SETTI M，et al. Provenance versus weathering control on the composition of tropical river mud (Southern Africa)[J]. Chemical Geology，2014，366：61−74.

[31] HARNOIS L. The CIW index：A new chemical index of weathering[J]. Sedimentary Geology，1988，55(3/4)：319−322.

[32] CULLERS R L. The geochemistry of shales，siltstones and sandstones of Pennsylvanian–Permian age，Colorado，USA：Implications for provenance and metamorphic studies[J]. Lithos，2000，51(3)：181−203.

[33] RASMUSSEN C，BRANTLEY S，RICHTER D D，et al. Strong climate and tectonic control on plagioclase weathering in granitic terrain[J]. Earth and Planetary Science Letters，2011，301(3/4)：521−530.

[34] YANG Jianghai，CAWOOD P A，DU Yuansheng，et al. Global continental weathering trends across the Early Permian glacial to postglacial transition：Correlating high– and low–paleolatitude sedimentary records[J]. Geology，2014，42(10)：835−838.

[35] FRANK T D，FIELDING C R，WINGUTH A M E，et al. Pace，magnitude，and nature of terrestrial climate change through the end–Permian extinction in southeastern Gondwana[J]. Geology，2021，49(9)：1089−1095.

[36] LI Chao，YANG Shouye. Is chemical index of alteration (CIA) a reliable proxy for chemical weathering in global drainage basins?[J]. American Journal of Science，2010，310(2)：111−127.

[37] 申博恒，沈树忠，吴琼，等. 华北板块石炭纪–二叠纪地层时间框架[J]. 中国科学：地球科学，2022，52(7)：1181−1212.

SHEN Boheng，SHEN Shuzhong，WU Qiong，et al. Carboniferous and Permian integrative stratigraphy and timescale of North China Block[J]. Science China：Earth Sciences，2022，52(7)：1181−1212.

[38] GUO Wenwei，TONG Jinnan，HE Qi，et al. Late Permian–Middle Triassic magnetostratigraphy in North China and its implications for terrestrial–marine correlations[J]. Earth and Planetary Science Letters，2022，585：117519.

[39] 刘超，孙蓓蕾，曾凡桂. 太原西山上二叠统–下三叠统地层最大沉积年龄的碎屑锆石U–Pb定年约束[J]. 地质学报，2014，88(8)：1579−1587.

LIU Chao，SUN Beilei，ZENG Fangui. Constraints on U–Pb dating of detrital zircon of the maximum depositional age for Upper Permian to Lower Triassic strata in Xishan，Taiyuan[J]. Acta Geologica Sinica，2014，88(8)：1579−1587.

[40] 冯志强，刘永江，王权，等. 华北板块中部晚二叠世–早三叠世砂岩碎屑锆石U–Pb定年及物源判别[J]. 地球科学，2023，48(4)：1288−1306.

FENG Zhiqiang，LIU Yongjiang，WANG Quan，et al. Detrial zircon U–Pb dating and provenance analysis for Late Permian–Early Triassic sandstone in central North China Craton[J]. Earth Science，2023，48(4)：1288−1306.

[41] KAIHO K，KAJIWARA Y，NAKANO T，et al. End–Permian catastrophe by a bolide impact：Evidence of a gigantic release of sulfur from the mantle[J]. Geology，2001，29(9)：815−818.

[42] ZHU Zhicai，LIU Yongqing，KUANG Hongwei，et al. Altered fluvial patterns in North China indicate rapid climate change linked to the Permian–Triassic mass extinction[J]. Scientific Reports，2019，9：16818.

[43] WU Qiong，RAMEZANI J，ZHANG Hua，et al. High–precision U–Pb age constraints on the Permian floral turnovers，paleoclimate change，and tectonics of the North China Block[J]. Geology，2021，49(6)：677−681.

[44] NESBITT H W，YOUNG G M. Prediction of some weathering trends of plutonic and volcanic rocks based on thermodynamic and kinetic considerations[J]. Geochimica et Cosmochimica Acta，1984，48(7)：1523−1534.

[45] GAO Shan，LUO Tingchuan，ZHANG Benren，et al. Chemical composition of the continental crust as revealed by studies in East China[J]. Geochimica et Cosmochimica Acta，1998，62(11)：1959−1975.

[46] GARZANTI E，PADOAN M，PERUTA L，et al. Weathering geochemistry and Sr–Nd fingerprints of equatorial upper Nile and Congo muds[J]. Geochemistry，Geophysics，Geosystems，2013，14(2)：292−316.

[47] YANG Jianghai，CAWOOD P A，DU Yuansheng，et al. Early Wuchiapingian cooling linked to Emeishan basaltic weathering?[J]. Earth and Planetary Science Letters，2018，492：102−111.

[48] CAWOOD P A，NEMCHIN A A，FREEMAN M，et al. Linking source and sedimentary basin：Detrital zircon record of sediment flux along a modern river system and implications for provenance studies[J]. Earth and Planetary Science Letters，2003，210(1/2)：259−268.

[49] YANG Jianghai，CAWOOD P A，DU Yuansheng，et al. Reconstructing Early Permian tropical climates from chemical weathering indices[J]. Geological Society of America Bulletin，2016，128(5/6)：739−751.

[50] GIRTY G H，RIDGE D L，KNAACK C，et al. Provenance and depositional setting of Paleozoic chert and argillite，Sierra Nevada，California[J]. Journal of Sedimentary Research，1996，66(1)：107−118.

[51] HAYASHI K I，FUJISAWA H，HOLLAND H D，et al. Geochemistry of ~ 1. 9 Ga sedimentary rocks from northeastern Labrador，Canada[J]. Geochimica et Cosmochimica Acta，1997，61(19)：4115–4137.

[52] ARMSTRONG–ALTRIN J S，LEE Y I，KASPER–ZUBILLAGA J J，et al. Mineralogy and geochemistry of sands along the Manzanillo and El Carrizal beach areas，Southern Mexico：Implications for palaeoweathering，provenance and tectonic setting[J]. Geological Journal，2016，52(4)：559−582.

[53] BRACCIALI L，MARRONI M，LUCA P，et al. Geochemistry and petrography of western Tethys Cretaceous sedimentary covers (Corsica and Northern Apennines)：From source areas to configuration of margins[M]//ARRIBAS J，JOHNSSON M J，CRITELLI S. Sedimentary provenance and petrogenesis：Perspectives from petrography and geochemistry. Geological Society of America，2007.

[54] LI Yanan，SHAO Longyi，FIELDING C R，et al. The chemical index of alteration in Permo–Carboniferous strata in North China as an indicator of environmental and climate change throughout the Late Paleozoic Ice Age[J]. Global and Planetary Change，2023，221：104035.

[55] LUPKER M，FRANCE–LANORD C，GALY V，et al. Increasing chemical weathering in the Himalayan system since the Last Glacial Maximum[J]. Earth and Planetary Science Letters，2013，365：243−252.

[56] YANG Jianghai，CAWOOD P A，MONTAÑEZ I P，et al. Enhanced continental weathering and large igneous province induced climate warming at the Permo–Carboniferous transition[J]. Earth and Planetary Science Letters，2020，534：116074.

[57] LIU Jun，LI Xu，JIA Songhai，et al. The Jiyuan tetrapod fauna of the Upper Permian of China：2. Stratigraphy，taxonomical review，and correlation[J]. Vertebrata PalAsiatica，2014，52(3)：328−339 .

[58] RAMPINO M R，RODRIGUEZ S，BARANSKY E，et al. Global nickel anomaly links Siberian Traps eruptions and the latest Permian mass extinction[J]. Scientific Reports，2017，7：12416.

[59] REICHOW M K，PRINGLE M S，AL’MUKHAMEDOV A I，et al. The timing and extent of the eruption of the Siberian Traps large igneous province：Implications for the end–Permian environmental crisis[J]. Earth and Planetary Science Letters，2009，277(1/2)：9−20.

[60] TU Chenyi，CHEN Zhongqiang，RETALLACK G J，et al. Proliferation of MISS–related microbial mats following the end–Permian mass extinction in terrestrial ecosystems：Evidence from the Lower Triassic of the Yiyang area，Henan Province，North China[J]. Sedimentary Geology，2016，333：50−69.

[61] BURGESS S D，MUIRHEAD J D，BOWRING S A. Initial pulse of Siberian Traps sills as the trigger of the end–Permian mass extinction[J]. Nature Communications，2017，8：164.

[62] SHEN Jun，YIN Runsheng，ZHANG Shuang，et al. Intensified continental chemical weathering and carbon–cycle perturbations linked to volcanism during the Triassic–Jurassic transition[J]. Nature Communications，2022，13：299.

[63] RETALLACK G J. Permian and Triassic greenhouse crises[J]. Gondwana Research，2013，24(1)：90−103.