Coal Geology & Exploration
Abstract
Based on the analysis of geological characteristics of the study area, it is considered that the geological conditions of H2S occurrence are the capping effect of dense surrounding rock on the roof and floor, the water-conducting fractured zone is unable to guide the overlying aquifer, and the low degree of coal metamorphism is not conducive to H2S adsorption, resulting in maximum H2S concentration of about 0.001 4% in the main mined coal seam 4 during the construction of Yadian mine at the north of Binchang mining area. Through the analysis of sulfur distribution, sulfate type, groundwater, ground temperature and unsaturated hydrocarbons in the raw coal of No.4 coal seam, it is considered that the formation conditions of H2S in the study area are as follows: the ground temperature of 30-40℃ was suitable for the reproduction of SRB, sulfate provided the material basis, C2-C8 unsaturated hydrocarbon provided the energy and material conditions, weak alkaline ground water provided the living environment and BSR was easy to occur. It is judged that the H2S gas in the mine is caused by BSR type. By optimizing ventilation, grouting and plugging, strengthening drainage and spraying alkalinity and other measures, the H2S overrun is effectively prevented, and the health of workers and mine safety are guaranteed.
Keywords
Binchang mining area, low metamorphic bituminous coal, occurrence conditions of H2S, genetic type of H2S, genesis of sulfate bioreduction(BSR)
DOI
10.3969/j.issn.1001-1986.2020.05.003
Recommended Citation
LIU Huibin, HE Wanying, JIANG Bo,
et al.
(2020)
"H2S occurrence conditions and genetic types of low rank bituminous coal in Binchang mining area,"
Coal Geology & Exploration: Vol. 48:
Iss.
5, Article 4.
DOI: 10.3969/j.issn.1001-1986.2020.05.003
Available at:
https://cge.researchcommons.org/journal/vol48/iss5/4
Reference
[1] 专家解读编委会. 《煤矿安全规程》专家解读井工煤矿(2016修订版)[M]. 徐州:中国矿业大学出版社,2016. Expert Interpretation Editoral Committee. Expert interpretation of safety regulations for coal mines,Jinggong coal mine(2016 Revision)[M]. Xuzhou:China University of Mining and Technology Press,2016.
[2] 牛克胜,张建峰. 城市污水处理厂H2S气体的产生、危害及预防[J]. 中国沼气,2003,21(4):28-30. NIU Kesheng,ZHANG Jianfeng. Generation,harm and prevention of H2S gas in municipal sewage treatment plant[J]. China Biogas,2003,21(4):28-30.
[3] 戴金星,胡见义,贾承造,等. 科学安全勘探开发高H2S天然气田的建议[J]. 石油勘探与开发,2004,31(2):1-4. DAI Jinxing,HU Jianyi,JIA Chengzao,et al. Suggestions for scientifically and safely exploring and developing high H2S gas fields[J]. Petroleum Exploration and Development,2004,31(2):1-4.
[4] 崔中杰,傅雪海,刘文平,等. 煤矿瓦斯中H2S的成因危害与防治[J]. 煤矿安全,2006,37(9):45-47. CUI Zhongjie,FU Xuehai,LIU Wenping,et al. Causes,harm and prevention of H2S in coal mine gas[J]. Safety in Coal Mines,2006,37(9):45-47.
[5] 王可新,傅雪海. 煤矿瓦斯中H2S异常的治理方法分析[J]. 煤炭科学技术,2007,35(1):94-96. WANG Kexin,FU Xuehai. Analysis on control method of H2S anomaly in mine gas[J]. Coal Science and Technology,2007,35(1):94-96.
[6] 张广太. 煤矿硫化氢赋存机理及治理研究[D]. 太原:太原理工大学,2007. ZHANG Guangtai. Study on occurrence mechanism and treatment of hydrogen sulfide in coal mine[D]. Taiyuan:Taiyuan University of Technology,2007.
[7] 王建,王宁波,漆涛,等. 急倾斜煤层硫化氢气体侵蚀规律与综合治理[J]. 西安科技大学学报,2009,29(6):677-680. WANG Jian,WANG Ningbo,QI Tao,et al. Corrosion law and comprehensive prevention of hydrogen sulfide-gas from steep seam[J]. Journal of Xi'an University of Science and Technology,2009,29(6):677-680.
[8] 陈刚. 准噶尔盆地彩南地区深层低阶煤吸附特征及其影响因素[J]. 煤田地质与勘探,2016,44(2):50-54. CHEN Gang. The adsorption characteristics and affecting factors of deep low-rank coal in Cainan area of Junggar basin[J]. Coal Geology & Exploration,2016,44(2):50-54.
[9] 傅雪海,何也,刘小辉,等. 乌鲁木齐西山井田原位煤层瓦斯中H2S含量的影响因素及成因分析[J]. 中国煤炭地质,2015,27(1):28-30. FU Xuehai,HE Ye,LIU Xiaohui,et al. In-situ coal seam gas H2S content influencing factors and genetic analysis in Xishan minefield,Urumqi,Xinjiang[J]. Coal Geology of China,2015,27(1):28-30.
[10] LIU Aihua,FU Xuehai,WANG Kexin,et al. Investigation of coalbed methane potential in low-rank coal reservoirs-free and soluble gas contents[J]. Fuel,2013,112:14-22.
[11] 何也,傅雪海,路露. 不同煤级煤对H2S的吸附影响因素分析[J]. 煤矿安全,2015,46(11):149-151. HE Ye,FU Xuehai,LU Lu. Influencing Factors of different coal ranks on H2S adsorption[J]. Safety in Coal Mines,2015,46(11):149-151.
[12] WANG Boyang,QIN Yong,SHEN Jian,et al. Pore structure characteristics of low-and medium-rank coals and their differential adsorption and desorption effects[J]. Journal of Petroleum Science and Engineering,2018,165:1-12.
[13] 王可新,傅雪海. 我国煤矿瓦斯中H2S及CO2等异常的成因分析[J]. 煤矿安全,2006,37(10):47-50. WANG Kexin,FU Xuehai. Cause analysis of H2S and CO2 anomalies in coal mine gas in China[J]. Safety in Coal Mines,2006,37(10):47-50.
[14] 朱光有,张水昌,梁英波,等. 四川盆地威远气田硫化氢的成因及其证据[J]. 科学通报,2006,51(23):2780-2788. ZHU Guangyou,ZHANG Shuichang,LIANG Yingbo,et al. Stable sulfur isotopic composition of hydrogen sulfide and its genesis in Sichuan basin[J]. Chinese Science Bulletin,2006,51(23):2780-2788.
[15] 费安国,朱光有,张水昌,等. 全球含硫化氢天然气的分布特征及其形成主控因素[J]. 地学前缘,2010,17(1):350-360. FEI Anguo,ZHU Guangyou,ZHANG Shuichang,et al. Global distribution hydrogen sulphide bearing natural gas and the major factors controlling its formation[J]. Earth Science Frontiers,2010,17(1):350-360.
[16] 焦春林,傅雪海,葛燕燕,等. 我国煤矿瓦斯中H2S异常矿井的分布特征[J]. 黑龙江科技学院学报,2013,23(4):375-377. JIAO Chunlin,FU Xuehai,GE Yanyan,et al. Distribution characteristics of H2S anomaly area of coal mine gas in China[J]. Journal of Heilongjiang Institute of Science and Technology,2013,23(4):375-377.
[17] 王宇锋. 铁新井田太原组煤层硫化氢成因分析[J]. 辽宁工程技术大学学报(自然科学版),2015,34(10):1137-1142. WANG Yufeng. Analysis of hydrogen sulfide origin for coal seams of the Taiyuan Formation in Tiexin mine field[J]. Journal of Liaoning Technical University(Natural Science),2015,34(10):1137-1142.
[18] 朱光有,张水昌,马永生,等. TSR(H2S)对石油天然气工业的积极性研究:H2S的形成过程促进储层次生孔隙的发育[J]. 地学前缘,2006,13(3):141-149. ZHU Guangyou,ZHANG Shuichang,MA Yongsheng,et al. Effectiveness of thermochemical sulfate reduction on oil and gas industry a H2S formation accelerating development of the secondary pores in reservoirs[J]. Earth Science Frontiers,2006,13(3):141-149.
[19] CAI Chunfang,LI Kaikai,MA Anlai,et al. Distinguishing the Cambrian source rock from the Upper Ordovician:Evidence from sulfur isotopes and biomarkers in the Tarim basin[J]. Organic Geochemistry,2009,40(7):755-768.
[20] LIU Mingju,DENG Qigen,ZHAO Fajun. Origin of hydrogen sulfide in coal seams in China[J]. Safety Science,2012,50:668-673.
[21] 邓奇根,刘明举,崔学锋,等. 准噶尔盆地东南缘煤矿硫化氢气体成因研究[J]. 地学前缘,2017,24(5):395-401. DENG Qigen,LIU Mingju,CUI Xuefeng,et al. A study of hydrogen sulfide genesis in coal mine of southeastern margin of Junggar basin[J]. Earth Science Frontiers,2017,24(5):395-401.
[22] 苗永春,付玉凯. 煤矿硫化氢赋存机理及综合治理方法研究[J]. 煤炭技术,2015,34(3):227-230. MIAO Yongchun,FU Yukai. Study on hydrogen sulphide forming mechanism and comprehensive management in mine[J]. Coal Technology,2015,34(3):227-230.
[23] ORR W L. Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation:Study of big Horn basin Palaeozoic oils[J]. American Association of Petroleum Geologists Bulletin,1974,58:2295-2318.
[24] MACHEL H G,KROUSE H R,SASSEN R. Products and distinguishing criteria of bacterial and thermochemical sulfate reduction[J]. Applied Geochemistry,1995,10(4):373-389.
[25] 张辉,王冕,刘中一. 煤层硫化氢的BSR作用及其识别[J]. 中州煤炭,2013(1):38-40. ZHANG Hui,WANG Mian,LIU Zhongyi. The role of BSR in coal bed hydrogen sulfide and its identification of coal[J]. Zhongzhou Coal,2013(1):38-40.
[26] 刘明举,李国旗,HANI Mitri,等. 煤矿硫化氢气体成因类型探讨[J]. 煤炭学报,2011,36(6):978-983. LIU Mingju,LI Guoqi,HANI Mitri,et al. Genesis modes discussion of H2S gas in coal mines[J]. Journal of China coal society,2011,36(6):978-983.
[27] 赵义胜,张崇智. 西曲矿9号煤H2S气体治理[J]. 煤炭科学技术,2011,39(增刊1):26-29. ZHAO Yisheng,ZHANG Chongzhi. H2S gas control of Xiqu mine No.9 coal seam[J]. Coal Science and Technology,2011,39(Sup.1):26-29.
[28] 袁欣鹏,梁冰,孙维吉,等. 煤层注碱治理矿井硫化氢涌出危害研究[J]. 中国安全科学学报,2015,25(5):114-119. YUAN Xinpeng,LIANG Bing,SUN Weiji,et al. Research on control of mine hydrogen sulfide emission by injecting sodium bicarbonate solution into coal seams[J]. China Safety Science Journal,2015,25(5):114-119.
[29] 刘会彬,康维安,尹润生,等. 低阶煤矿区H2S异常成因及防治措施[J]. 煤炭技术,2017,36(10):95-98. LIU Huibin,KANG Wei'an,YIN Runsheng,et al. Genetic types and prevention measures of H2S anomaly in low rank coal mining area[J]. Coal Technology,2017,36(10):95-98.
[30] 翟所国,董曰喜,陈足章. 浅谈矿井中硫化氢治理技术[J]. 煤矿现代化,2007(1):58-59. ZHAI Suoguo,DONG Yuexi,CHEN Zuzhang. Brief discussion on treatment technology of hydrogen sulfide in mine[J]. Coal Mine Modernization,2007(1):58-59.
[31] 刘平,胡敏. 煤矿硫化氢的形成机理及综合防治措施[J]. 中州煤炭,2009(5):69-70. LIU Ping,HU Min. Formation mechanism of sulfureted hydrogen in coal mine and comprehensive control countermeasures[J]. Zhongzhou Coal,2009(5):69-70.
[32] 陈足章,赵庆民,董曰喜. 矿井中H2S综合治理技术[J]. 煤矿安全,2012,43(增刊1):85-88. CHEN Zuzhang,ZHAO Qingmin,DONG Yuexi. Comprehensive contorl techonlogy of H2S in mine[J]. Safety in Coal Mines,2012,43(Sup.1):85-88.
[33] YAO Yanbin,LIU Dameng,YAN Taotao. Geological and hydrogeological controls on the accumulation of coalbed methane in the Weibei field,southeastern Ordos basin[J]. International Journal of Coal Geology,2014,121:148-159.
[34] 田冲,汤达祯,周志军,等. 彬长矿区水文地质特征及其对煤层气的控制作用[J]. 煤田地质与勘探,2012,40(1):43-46. TIAN Chong,TANG Dazhen,ZHOU Zhijun,et al. Hydrogeological characteristics and their control on coalbed methane in Binchang mining area[J]. Coal Geology & Exploration,2012,40(1):43-46.
[35] 杨新辉. 黄陇煤田煤层气储层特征[J]. 煤田地质与勘探,2015,43(4):41-45. YANG Xinhui. Characteristics of CBM reservoir in Huangling-Longxian coalfield[J]. Coal Geology & Exploration,2015,43(4):41-45.
[36] 胡军,郑宝山,王明仕,等. 中国煤中硫的分布特征及成因[J]. 煤炭转化,2005,28(4):1-6. HU Jun,ZHENG Baoshan,WANG Mingshi,et al. Distribution and forming cause of sulpher in Chinese coals[J]. Coal Conversion,2005,28(4):1-6.
[37] 宫景华,李维安,CATHERINE B,等. 石油微生物中有利和不利于采油的微生物[J]. 国外油田工程,2001,17(4):1-5. GONG Jinghua,LI Wei'an,CATHERINE B,et al. Microorganisms that are beneficial and unfavorable to oil recovery in petroleum microorganisms[J]. Foreign Oilfield Engineering,2001,17(4):1-5.
[38] MACHEL H G. Bacterial and thermochemical sulfate reduction in diagenetic settings:Old and new insights[J]. Sedimentary Geology,2001,140:143-175.
[39] 潘旭方,郭庆,孙磊. 金属矿山尾矿充填区硫化氢气产生机理及治理技术研究[J]. 现代矿业,2009(9):79-81. PAN Xufang,GUO Qing,SUN Lei. Study of production mechanism of hydrogen sulfide in tailing filing area of metal mines and control methods[J]. Morden Mining,2009(9):79-81.
[40] 何宝林. 彬长矿区白垩系地下水水质变化特征[J]. 中国煤田地质,2002,14(3):33-35. HE Baolin. Water quality change features of ground water in Cretaceous system of Binchang mining area[J]. Coal Geology of China,2002,14(3):33-35.
[41] JOBSON A M,COOK F D,WESTLAKE D W S. Interaction of aeroic and anaerobic bacteria in petroleum biodegradation[J]. Chemical Geology,1979,24(3/4):353-365.
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