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Coal Geology & Exploration

Abstract

Objective and Methods Coal graphitization is a multi-stage process with abrupt changes rather than linear evolution. So far, its inherent driving mechanisms have not yet been fully elucidated. Notably, twisted graphene was observed in the process of coal graphitization in 2025, providing a new opportunity to reveal the essence of this structural transformation. Results and Conclusions By combining previous research results, this study proposes a novel coal graphitization model that consists of condensation, alignment, stacking, and twisting (CAST). The four parts of the CAST model are organically integrated, collectively forming a continuous and dynamic evolutionary process. Most especially, no absolute boundaries exist among alignment, stacking, and twisting; instead, the three processes interact manually, jointly controlling and adjusting the progress and degree of coal graphitization. Theoretically, the novel CAST model clarifies the fundamental nature of coal graphitization as evolution from short-range disorder into long-range order. Therefore, this model provides a new perspective for gaining deep insights into the coal graphitization process and even enables the reconstruction of the underlying mechanisms of coalification. Practically, this novel model can direct the research focus toward the performance of coal as raw materials rather than merely as fuels, thus maximizing its value as “black gold”.

Keywords

coal graphitization, novel CAST model, twisting graphene, stacking, alignment

DOI

10.12363/issn.1001-1986.26.05.0284

Reference

[1] 王绍清,王小令,沙吉顿,等. 煤石墨化:结构和差异性演化[J]. 煤炭学报,2022,47(12):4300−4312 WANG Shaoqing,WANG Xiaoling,SHA Jidun,et al. Coal graphitization:Structures and their differential evolution[J]. Journal of China Coal Society,2022,47(12):4300−4312

[2] CHEN Hao,WANG Shaoqing,ZHANG Xiaomei,et al. A study of chemical structural evolution of thermally altered coal and its effect on graphitization[J]. Fuel,2021,283:119295.

[3] OBERLIN A. Carbonization and graphitization[J]. Carbon,1984,22(6):521−541.

[4] 秦勇. 中国高煤级煤的显微岩石学特征及结构演化[D]. 徐州:中国矿业大学,1992. QIN Yong. Micropetrological characteristics and structural evolution of high–rank coals in China[D]. Xuzhou:China University of Mining and Technology,1992.

[5] DEBYE P,SCHERRER P. Interferenzen an regellos orientierten Teilchen im Röntgenlicht. III[J]. Physikalische Zeitschrift,1917,18:291−301.

[6] WARREN B E. X–ray diffraction in random layer lattices[J]. Physical Review,1941,59(9):693−698.

[7] FRANKLIN R E. Crystallite growth in graphitizing and non–graphitizing carbons[J]. Proceedings of the Royal Society of London Series A Mathematical and Physical Sciences,1951,209(1097):196−218.

[8] ERGUN S. Structure of carbon[J]. Carbon,1968,6(2):141−159.

[9] OBERLIN A,ROUCHY J P. Transformation des carbones non graphitables par traitement thermique en presence de fer[J]. Carbon,1971,9(1):39−46.

[10] OBERLIN A,TERRIERE G. Graphitization studies of anthracites by high resolution electron microscopy[J]. Carbon,1975,13(5):367−376.

[11] PAPPANO P J. A mechanism of Pennsylvania anthracite graphitization involving carbide formation and decomposition[D]. University Park:The Pennsylvania State University,2003.

[12] OUZILLEAU P,GHERIBI A E,CHARTRAND P. The graphitization temperature threshold analyzed through a second–order structural transformation[J]. Carbon,2016,109:896−908.

[13] VAN KREVELEN D W. Coal:Typology–physics–chemistry–constitution (3rd Edition)[M]. Amsterdam:Elsevier Science Publishers,1993.

[14] SZYMANOWITZ R. Edward Goodrich Acheson[J]. Journal of Chemical Education,1956,33(3):113.

[15] 钱树安. 略论炭素科学的形成和进展 Ⅱ. 炭素结构X光衍射研究的发展历史阶段[J]. 炭素,1995(3):1−8 QIAN Shu’an. A brief note on the formation and progress of carbon science II. Historical stages of the advances in carbon structure research using X–ray diffraction method[J]. Carbon,1995(3):1−8

[16] LI Jiuqing,QIN Yong,SHEN Jian,et al. Evolution of carbon nanostructures during coal graphitization:Insights from X–ray diffraction and high–resolution transmission electron microscopy[J]. Energy,2024,290:130316.

[17] 曹代勇,王路,刘志飞,等. 煤系石墨成矿机理与赋存规律[M]. 北京:地质出版社,2023.

[18] ZHANG Shuai,LIU Qinfu,ZHANG Hao,et al. Structural order evaluation and structural evolution of coal derived natural graphite during graphitization[J]. Carbon,2020,157:714−723.

[19] WANG Yuhui,YAO Suping. Effect of pressure on the evolution of vitrinite graphitized mesophases:An experimental study on anthracite under high temperature and pressure[J]. International Journal of Coal Geology,2023,267:104187.

[20] 李伍,杨文斌,战星羽,等. 煤有机大分子碳结构石墨化机制[J]. 煤炭学报,2023,48(2):855−868 LI Wu,YANG Wenbin,ZHAN Xingyu,et al. Graphitization mechanism of coal organic macromolecular carbon structure[J]. Journal of China Coal Society,2023,48(2):855−868

[21] GOMA J,OBERLIN A. Microtexture and structure of high temperature massive pyrocarbons prepared on graphite substrates[J]. Carbon,1985,23(1):85−90.

[22] LI Jiuqing,QIN Yong,CHEN Yilin,et al. HRTEM observation of morphological and structural evolution of aromatic fringes during the transition from coal to graphite[J]. Carbon,2022,187:133−144.

[23] 秦勇,姜波,宋党育,等. 高煤级煤碳结构13C NMR演化及其机理探讨[J]. 煤炭学报,1998,23(6):634−638 QIN Yong,JIANG Bo,SONG Dangyu,et al. Characteristics and mechanism on the 13C NMR evolution of the carbon structure in the high–rank coals[J]. Journal of China Coal Society,1998,23(6):634−638

[24] ATRIA J V,RUSINKO F,SCHOBERT H H. Structural ordering of Pennsylvania anthracites on heat treatment to 2000–2900 ℃[J]. Energy & Fuels,2002,16(6):1343−1347.

[25] LOPES DOS SANTOS J M B,PERES N M R,CASTRO NETO A H. Graphene bilayer with a twist:Electronic structure[J]. Physical Review Letters,2007,99(25):256802.

[26] BISTRITZER R,MACDONALD A H. Moiré bands in twisted double–layer graphene[J]. Proceedings of the National Academy of Sciences of the United States of America,2011,108(30):12233−12237.

[27] CAO Yuan,FATEMI V,DEMIR A,et al. Correlated insulator behaviour at half–filling in magic–angle graphene superlattices[J]. Nature,2018,556(7699):80−84.

[28] CAO Yuan,FATEMI V,FANG Shiang,et al. Unconventional superconductivity in magic–angle graphene superlattices[J]. Nature,2018,556(7699):43−50.

[29] SONG Dian,LI Jie,LIU Kun,et al. Advanced synthesis and influencing mechanisms of distinctive electrical performance for twisted graphene systems:A layer–oriented review[J]. Diamond and Related Materials,2025,151:111853.

[30] WANG Shaoqing,SHA Jidun,LYU Wenjia,et al. The stacking of graphene in a pseudocrystallite[J]. Carbon,2025,238:120273.

[31] SHA Jidun,WANG Shaoqing,ZHANG Xiaomei,et al. Evidence of a connection between turbostratic structure and twisted graphene[J]. Crystal Growth & Design,2025,25(17):7074−7080.

[32] WANG Shaoqing,CHEN Hao,WANG Xiaoling,et al. Elementary evolution in coal under natural conditions:Coals affected by igneous intrusions[J]. Fuel,2023,334:126708.

[33] ZHANG Xiaomei,WANG Shaoqing,CHEN Hao,et al. Observation of carbon nanostructure and evolution of chemical structure from coal to graphite by high temperature treatment,using componential determination,X–ray diffraction and high–resolution transmission electron microscope[J]. Fuel,2023,332:126145.

[34] RODRIGUES S,SUÁREZ–RUIZ I,MARQUES M,et al. Microstructural evolution of high temperature treated anthracites of different rank[J]. International Journal of Coal Geology,2011,87(3/4):204−211.

[35] GONZÁLEZ D,MONTES–MORÁN M A,GARCIA A B. Graphite materials prepared from an anthracite:A structural characterization[J]. Energy & Fuels,2003,17(5):1324−1329.

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