Coal Geology & Exploration
Abstract
Background The dynamic metamorphism of coals, a significant type of coal metamorphism, represents a fundamental research topic of coal geology. The research achievements have been widely applied in fields such as coal resource evaluation, the prevention and control of coal mine gas, and the exploration and exploitation of coalbed methane (CBM), holding great significance for gaining a deep understanding of the microscopic mechanisms underlying coal deformation and metamorphism, coal and gas outbursts, and CBM occurrence. Method Based on a literature survey and analysis, this study presents a systematic review of the development history of research on the dynamic metamorphism of coals. Accordingly, this study summarizes the indicators, pathways, and mechanisms of the dynamic metamorphism, analyzes its classic applications and extensions in related fields, and proposes future trends in its research. Advances and Prospects Research on the dynamic metamorphism of coals has undergone nearly a century of development. With the determination of identification indicators dominated by the microscopic deformations and macromolecular structures of coals, the dynamic metamorphism theory of coals has been gradually established and recognized. The pathways and molecular-level mechanisms of the dynamic metamorphism have been thoroughly revealed, yielding abundant research achievements and systematic research methods. The results indicate that the dynamic metamorphism of coals occurs throughout the coal evolution from peat to graphite, with the different chemical structures of organic matter across various evolutionary stages identified as a major inherent reason for the differentiated evolution characteristics of the dynamic metamorphism. Coal deformation and metamorphism feature internal consistency. Specifically, the mechanisms underlying coal deformation affect the characteristics and degree of the dynamic metamorphism, while the metamorphism represents the essence of the microscopic processes and mechanisms of coal deformation. Tectonic stress plays a key role in controlling the deformation and dynamic metamorphism of coals, with its magnitude and property, along with the deformation environment, determining the deformation and dynamic metamorphism intensities of coals. The dynamic metamorphism of coals changes the occurrence state and content of methane while also enhancing the heterogeneity of gas/CBM occurrence and distribution, thereby increasing both the risk of coal and gas outbursts and the difficulty of CBM exploration and exploitation. The dynamic response characteristics of coal molecular structures at varying levels are determined, enriching and improving the dynamic metamorphism theory of coals and facilitating the understanding of actual coal molecular structures. Prospects In the future, research on the dynamic metamorphism of coals should consider both the molecular structural differences of coal macerals and the catalytic effects of inorganic minerals in coals by combining the systematic chemical theory on coal molecular structures, especially the quantitative characterization of supramolecular structure evolution. Furthermore, it is necessary to continuously enhance fundamental theory research using advanced methods, such as molecular simulation and machine learning. Research on the dynamic metamorphism of coals should focus on national strategic demands for the goals of peak carbon dioxide emissions and carbon neutrality, as well as the optimization and adjustment of the national energy mix. This involves accelerating the application of the research achievements in emerging fields, such as intelligent and green coal mining, carbon sequestration, hydrogen storage, and the exploration and exploitation of minerals paragenetic and associated with coal measures, and broadening the research scope. These efforts will facilitate the rapid transformation and development of the coal industry.
Keywords
coal, dynamic metamorphism, tectonic stress, tectonically deformed coal, macromolecular structure
DOI
10.12363/issn.1001-1986.26.02.0079
Recommended Citation
LIU Hewu, JIANG Bo, SONG Yu,
et al.
(2026)
"Theoretical research advances and applications of the dynamic metamorphism of coals,"
Coal Geology & Exploration: Vol. 54:
Iss.
6, Article 8.
DOI: 10.12363/issn.1001-1986.26.02.0079
Available at:
https://cge.researchcommons.org/journal/vol54/iss6/8
Reference
[1] 曹代勇,唐跃刚. 煤中应变各向异性条纹的发现及意义[J]. 煤田地质与勘探,1994,22(3):14−16 CAO Daiyong,TANG Yuegang. The strain optical anisotropic lamella in coal and its geological significance[J]. Coal Geology & Exploration,1994,22(3):14−16
[2] 曹代勇,李小明,张守仁. 构造应力对煤化作用的影响:应力降解机制与应力缩聚机制[J]. 中国科学(D辑:地球科学),2006,36(1):59−68
[3] 姜波,秦勇,琚宜文,等. 构造煤化学结构演化与瓦斯特性耦合机理[J]. 地学前缘,2009,16(2):262−271 JIANG Bo,QIN Yong,JU Yiwen,et al. The coupling mechanism of the evolution of chemical structure with the characteristics of gas of tectonic coals[J]. Earth Science Frontiers,2009,16(2):262−271
[4] 阎文英. 关于煤变质作用类型划分的初步商榷:并论予西煤变质作用[J]. 西安矿业学院学报,1983,3(2):68−76
[5] 杨起,吴冲龙,汤达祯,等. 中国煤变质作用[J]. 地球科学,1996,21(3):311−319 YANG Qi,WU Chonglong,TANG Dazhen,et al. Coal metamorphism in China[J]. Earth Science,1996,21(3):311−319
[6] 缪奋. 煤的构造应力变质作用[J]. 煤炭科学技术,1979,7(2):44−48
[7] 袁耀庭,曲星武,王金城. 煤的变质作用雏议[J]. 煤炭学报,1980,5(1):1−8 YUAN Yaoting,QU Xingwu,WANG Jincheng. On coal metamorphism[J]. Journal of China Coal Society,1980,5(1):1−8
[8] 李焕同,李搛倬,李阳,等. 湘中地区煤系变形及煤变质作用特征分析[J]. 西安科技大学学报,2017,37(6):886−891 LI Huantong,LI Jianzhuo,LI Yang,et al. Coal seam deformation and metamorphism characteristics in central Hunan[J]. Journal of Xi'an University of Science and Technology,2017,37(6):886−891
[9] 朱兴珊,徐凤银,陈长国. 南桐矿区龙潭煤系热演化及煤变质研究[J]. 中国矿业大学学报,1996,25(4):38−44 ZHU Xingshan,XU Fengyin,CHEN Changguo. Study on thermal evolution and coal metamorphism of the Longtan coal series in Nantong mining area[J]. Journal of China University of Mining & Technology,1996,25(4):38−44
[10] 毕华,彭格林,赵志忠,等. 湘中涟源煤盆测水组煤动力变质作用的特征及其成因探讨[J]. 地质地球化学,1997,25(2):36−40 BI Hua,PENG Gelin,ZHAO Zhizhong,et al. Characteristics of dynamometamorphism of Ceshui Formation coal and its genesis in Lianyuan Coal Basin,central Hunan[J]. Geology–Geochemistry,1997,25(2):36−40
[11] 张玉贵,曹运兴,李凯琦. 构造煤顺磁共振波谱特征初探[J]. 焦作工学院学报,1997,16(2):37−40 ZHANG Yugui,CAO Yunxing,LI Kaiqi. Probing into electron paramagnetic resonance spectrum features of disturbed coal[J]. Journal of Jiaozuo Institute of Technology,1997,16(2):37−40
[12] 陈善庆. 鄂湘粤桂晚二叠世煤的岩石组成及其变质的初步研究[J]. 中国地质科学院宜昌地质矿产研究所所刊,1984(8):98−114 CHEN Shanqing. The studies of the petrographical composition of the Late Permian coal and its metamorphism in Hubei,Hunan,Guangdong and Guangxi,China[J]. Bulletin of Yichang Institute of Mineral Resources,Chinese Academy of Geological Sciences,1984(8):98−114
[13] 缪奋. 中国东部煤的构造应力变质作用[J]. 煤炭学报,1988,13(2):1−11 MIAO Fen. Coal metamorphism resulted from tectonic stress in East China[J]. Journal of China Coal Society,1988,13(2):1−11
[14] 胡希廉. 山西煤种分布规律及其变质成因[J]. 地质知识,1957(9):15−19
[15] 蒋博宇. 广西晚二叠世煤变质规律及变质作用的探讨[J]. 广西煤炭,1997,15(3):132−135
[16] 曹运兴,张玉贵,李凯琦,等. 构造煤的动力变质作用及其演化规律[J]. 煤田地质与勘探,1996,24(4):15−18 CAO Yunxing,ZHANG Yugui,LI Kaiqi,et al. Tectonic coal dynamometamorphism and evolutionary process[J]. Coal Geology & Exploration,1996,24(4):15−18
[17] 张玉贵. 构造煤演化与力化学作用[D]. 太原:太原理工大学,2006. ZHANG Yugui. Evolution of deformed coal and process of coal mechanochemistry[D]. Taiyuan:Taiyuan University of Technology,2006.
[18] 琚宜文,林红,李小诗,等. 煤岩构造变形与动力变质作用[J]. 地学前缘,2009,16(1):156−166 JU Yiwen,LIN Hong,LI Xiaoshi,et al. Tectonic deformation and dynamic metamorphism of coal[J]. Earth Science Frontiers,2009,16(1):156−166
[19] 林红,琚宜文,侯泉林,等. 脆、韧性变形构造煤的激光Raman光谱特征及结构成分响应[J]. 自然科学进展,2009,19(10):1117−1125
[20] 侯泉林,雒毅,韩雨贞,等. 煤的变形产气机理探讨[J]. 地质通报,2014,33(5):715−722 HOU Quanlin,LUO Yi,HAN Yuzhen,et al. Gas production mechanism in the process of coal tectonic deformation[J]. Geological Bulletin of China,2014,33(5):715−722
[21] 曹代勇,琚宜文,夏玉成,等. 中国煤田构造研究的史实概览、主要进展与前景展望[J]. 煤田地质与勘探,2025,53(5):1−23 CAO Daiyong,JU Yiwen,XIA Yucheng,et al. Historical overview,advancements,and future prospects of coalfield structure research in China[J]. Coal Geology & Exploration,2025,53(5):1−23
[22] 杨起,任德贻. 中国煤变质问题的探讨[J]. 煤田地质与勘探,1981,9(1):1−10
[23] 依·弗·多洛辛. 煤的区域变质规律[J]. 北京矿业学院学报,1956(1):3−13
[24] 肖贤明,任德贻. 滑动构造引起煤动力变质作用的发现及初步研究[J]. 煤田地质与勘探,1987,15(4):29−34
[25] TEICHMÜLLER M,TEICHMÜLLER R. Geological causes of coalification[M]//Coal science. Washington,D. C. :American Chemical Society,1966:133–155.
[26] 趙兴田,刘乃隆. 記“華北煤种牌号之帶狀分布及其地質因素”学術討論会[J]. 地质知识,1957(7):4
[27] 吴传荣. 回顾王竹泉教授在煤变质方面的贡献[J]. 煤田地质与勘探,1991,19(2):2−5
[28] 缪奋,张伍侪. 构造体系与煤的变质[J]. 煤田地质与勘探,1977,5(6):82−86
[29] 方道恕,潘相铨,陈宝龄,等. 华东区二叠纪煤变质规律及变质作用[J]. 煤田地质与勘探,1984,12(6):24−28
[30] 煤炭部地质勘探研究所湘赣课题煤质组. 试谈湘赣晚二迭世煤的构造应力变质[J]. 煤田地质与勘探,1977,5(6):87−94
[31] 缪奋. 煤的构造应力变质作用的地质模式[J]. 科学通报,1980,25(3):128−130
[32] 袁耀庭. 简论煤的热力变质[J]. 煤田地质与勘探,1978,6(3):33−36
[33] 袁三畏. 贵州某地区煤的变质特征[J]. 煤田地质与勘探,1975,3(6):53−58
[34] 朱榔如. 福建省天湖山煤田煤的变质问题[J]. 煤田地质与勘探,1981,9(3):32−38
[35] 钟宁宁,曹代勇. 华北聚煤区南部煤变质作用类型及其控制因素探讨[J]. 中国矿业大学学报,1992,21(3):86−93 ZHONG Ningning,CAO Daiyong. Discussion on the coal metamorphic types and their controlled factors in the southern part of the North China coal–bearing region[J]. Journal of China University of Mining & Technology,1992,21(3):86−93
[36] 杨起,潘治贵,翁成敏,等. 区域岩浆热变质作用及其对我国煤质的影响[J]. 现代地质,1987,1(1):123−130 YANG Qi,PAN Zhigui,WENG Chengmin,et al. Telemagmatic metamorphism and its effects on Chinese coal properties[J]. Geoscience,1987,1(1):123−130
[37] 李产林. 四川晚三叠世煤变质问题的研究[J]. 现代地质,1990,4(2):98−104 LI Chanlin. Research on coal metamorphism of the Late Triassic in Sichuan[J]. Geoscience,1990,4(2):98−104
[38] 谭永杰. 四川南桐煤田煤变质的古地温场特征及其形成的构造条件探讨[D]. 西安:西安科技大学,1987. TAN Yongjie. On the paleogeothermal field of coal metamorphism and its forming structural conditions in Nantong coalfield of Sichuan[D]. Xi’an:Xi’an University of Science and Technology,1987.
[39] 秦勇,金奎励. 滇西腾冲盆地中晚更新世泥炭向软褐煤的转化特征及异常煤化作用[J]. 沉积学报,1989,7(3):73−81 QIN Yong,JIN Kuili. Characteristics and anomalous coalification of the transformation from the Middle and Late Pleistocene peat to soft brown coal in Tengchong Basin[J]. Acta Sedimentologica Sinica,1989,7(3):73−81
[40] BUSTIN R M. Heating during thrust faulting in the rocky mountains:Friction or fiction?[J]. Tectonophysics,1983,95(3/4):309−328.
[41] MUKHERJEE A K,ALAM M M,GHOSE S. Gondwana coals of Bhutan Himalaya–Occurrence,properties and petrographic characteristics[J]. International Journal of Coal Geology,1988,9(3):287−304.
[42] 王德本. 略论煤的变质问题[J]. 中国煤田地质,2002,14(2):9−12 WANG Deben. Brief introduction on metamorphic problems of coal[J]. Coal Geology of China,2002,14(2):9−12
[43] 潘伟尔. 湘中南地区煤变质与地质构造关系的研究[J]. 地质论评,2000,46(1):64−70 PAN Wei’er. A research on the relationship between the metamorphism of coal and tectonic structures in central–south Hunan Province[J]. Geological Review,2000,46(1):64−70
[44] PETZOUKHA Y,SELIVANOV O. Promotion of petroleum formation by source rock deformation[J]. Org Geochem Advance and Application in the Natural Environment. Manckerster:Manckerster University Press,1991:312–314.
[45] ROSS J V,BUSTIN R M. The role of strain energy in creep graphitization of anthracite[J]. Nature,1990,343(6253):58−60.
[46] WILKS K R,MASTALERZ M,BUSTIN R M,et al. The role of shear strain in the graphitization of a high–volatile bituminous and an anthracitic coal[J]. International Journal of Coal Geology,1993,22(3/4):247−277.
[47] BUSTIN R M,ROUZAUD J N,ROSS J V. Natural graphitization of anthracite:Experimental considerations[J]. Carbon,1995,33(5):679−691.
[48] SAJGÓ C,MCEVOY J,WOLFF G A,et al. Influence of temperature and pressure on maturation processes–I. Preliminary report[J]. Organic Geochemistry,1986,10(1/2/3):331−337.
[49] HUCK G,PATTEISKY K. Coalification reactions under pressure[J]. Fortschr. Geol. Rheinl. Westfalen (West Germany),1964(12):551−558.
[50] MONTHIOUX M,LANDAIS P,MONIN J C. Comparison between natural and artificial maturation series of humic coals from the Mahakam delta,Indonesia[J]. Organic Geochemistry,1985,8(4):275−292.
[51] 姜波,秦勇,金法礼. 高温高压实验变形煤XRD结构演化[J]. 煤炭学报,1998,23(2):188−193 JIANG Bo,QIN Yong,JIN Fali. XRD analysis of the structural evolution of deformed coal samples tested under high temperature and high confined pressure[J]. Journal of China Coal Society,1998,23(2):188−193
[52] 姜波,秦勇,宋党育,等. 高煤级构造煤的XRD结构及其构造地质意义[J]. 中国矿业大学学报,1998,27(2):115−118 JIANG Bo,QIN Yong,SONG Dangyu,et al. XRD structure of high rank tectonic coals and its implication to structural geology[J]. Journal of China University of Mining & Technology,1998,27(2):115−118
[53] 秦勇,姜波,宋党育,等. 高煤级煤碳结构13CNMR演化及其机理探讨[J]. 煤炭学报,1998,23(6):634−638 QIN Yong,JIANG Bo,SONG Dangyu,et al. Characteristics and mechanism on the 13CNMR evolution of the carbon structure in the high–rank coals[J]. Journal of China Coal Society,1998,23(6):634−638
[54] 姜波,秦勇. 实验变形煤结构的13CNMR特征及其构造地质意义[J]. 地球科学,1998,23(6):579−582 JIANG Bo,QIN Yong. 13CNMR characteristics of structures of the experimental deformed coals and their significance of structural geology[J]. Earth Science,1998,23(6):579−582
[55] 姜波,秦勇. 实验变形煤结构演化的电子顺磁共振研究[J]. 长春科技大学学报,1998,28(4):411−416 JIANG Bo,QIN Yong. Research on electron paramagnetic resonance of structure evolution of experimental deformed coals[J]. Journal of Changchun University of Science and Technology,1998,28(4):411−416
[56] 姜波,秦勇. 变形煤的EPR结构演化及其构造地质意义[J]. 高校地质学报,1999,5(3):334−339 JIANG Bo,QIN Yong. EPR structural evolution of deformed coals and its significance in structural geology[J]. Geological Journal of China Universities,1999,5(3):334−339
[57] 姜峰,杜建国,王万春,等. 高温超高压模拟实验研究–Ⅱ. 高温高压下烷烃产物的演化特征[J]. 沉积学报,1998,16(4):145−148 JIANG Feng,DU Jianguo,WANG Wanchun,et al. The study on high–pressure–high–temperature aqueous pyrolysis Ⅱ. Evolutionary characteristics of alkane generated from organic matter under high temperature and high pressure[J]. Acta Sedimentologica Sinica,1998,16(4):145−148
[58] 胡善亭,杨起,潘治贵. 鸡西煤田深部动力学特征与煤的变质作用[J]. 东北煤炭技术,1996(1):57−60 HU Shanting,YANG Qi,PAN Zhigui. The characteristics of crust dynamics and the coal metamorphism in Jixi coalfield[J]. Coal Technology of Northeast China,1996(1):57−60
[59] BUSTIN R M,ROSS J V,ROUZAUD J N. Mechanisms of graphite formation from kerogen:Experimental evidence[J]. International Journal of Coal Geology,1995,28(1):1−36.
[60] 周建勋,邵震杰,王桂梁. 煤光性组构的实验变形研究[J]. 科学通报,1993,38(2):147−150
[61] 周建勋,王桂梁,邵震杰. 煤高温高压变形实验及其构造地质意义[J]. 地球物理学进展,1993,8(4):54−60 ZHOU Jianxun,WANG Guiliang,SHAO Zhenjie. Coal deformation experiment under high temperature and confining pressure and its tectonic implications[J]. Progress in Geophysics,1993,8(4):54−60
[62] 周建勋,邵震杰,王桂梁. 实验变形煤的光性组构分析[J]. 地质科学,1994,29(3):276−290 ZHOU Jianxun,SHAO Zhenjie,WANG Guiliang. Analysis of optical fabrics in experimentally deformed coals[J]. Chinese Journal of Geology,1994,29(3):276−290
[63] 姜波,秦勇,金法礼. 高温高压下煤超微构造的变形特征[J]. 地质科学,1998,33(1):17−24 JIANG Bo,QIN Yong,JIN Fali. Deformation characteristics of super–microstructures of coal under the condition of high temperature and confining pressure[J]. Chinese Journal of Geology,1998,33(1):17−24
[64] 姜波,金法礼,周强,等. 煤镜质组反射率光性组构变形实验研究[J]. 煤田地质与勘探,1997,25(2):11−15 JIANG Bo,JIN Fali,ZHOU Qiang,et al. Experimental research on deformation of optical fabric of coal vitrinite reflectance[J]. Coal Geology & Exploration,1997,25(2):11−15
[65] 曹代勇,刘志飞,王安民,等. 构造物理化学条件对煤变质作用的控制[J]. 地学前缘,2022,29(1):439−448 CAO Daiyong,LIU Zhifei,WANG Anmin,et al. Control of coal metamorphism by tectonic physicochemical conditions[J]. Earth Science Frontiers,2022,29(1):439−448
[66] 曹运兴. 煤的韧性变形机制及其识别标志[J]. 焦作矿业学院学报,1992,11(3):39−44 CAO Yunxing. The ductility deformation mechanism and distinguished marks of coal[J]. Journal of Jiaozuo Mining Institute,1992,11(3):39−44
[67] 侯泉林,张子敏. 关于“糜棱煤”概念之探讨[J]. 焦作矿业学院学报,1990,9(2):21−26 HOU Quanlin,ZHANG Zimin. The study of the concept of mylon–coal[J]. Journal of Henan Polytechnic University (Natural Science),1990,9(2):21−26
[68] 姜波,琚宜文. 构造煤结构及其储层物性特征[J]. 天然气工业,2004,24(5):27−29 JIANG Bo,JU Yiwen. Tectonic coal structure and its petrophysical features[J]. Natural Gas Industry,2004,24(5):27−29
[69] 李康,钟大赉. 煤岩的显微构造特征及其与瓦斯突出的关系:以南桐鱼田堡煤矿为例[J]. 地质学报,1992,66(2):148−157 LI Kang,ZHONG Dalai. Microstructures of coal and their relation with gas outbursts:A case study of the Yutianbao coal mine,Nantong[J]. Acta Geologica Sinica,1992,66(2):148−157
[70] 苏现波,谢洪波,华四良. 煤体脆–韧性变形微观识别标志[J]. 煤田地质与勘探,2003,31(6):18−21 SU Xianbo,XIE Hongbo,HUA Siliang. The microscopic identification of coal brittle–ductile deformation[J]. Coal Geology & Exploration,2003,31(6):18−21
[71] 曹代勇,张守仁,任德贻. 构造变形对煤化作用进程的影响:以大别造山带北麓地区石炭纪含煤岩系为例[J]. 地质论评,2002,48(3):313−317 CAO Daiyong,ZHANG Shouren,REN Deyi. The influence of structural deformation on coalification:A case study of Carboniferous coal measures in the northern foothills of the Dabie Orogenic Belt[J]. Geological Review,2002,48(3):313−317
[72] 曹代勇,张守仁. 大别山北麓高煤级煤的变形–变质类型[J]. 地质科学,2003,38(4):470−477 CAO Daiyong,ZHANG Shouren. Deformation–metamorphic types of high–rank coal in northern slope of the Dabie mountains,Central China[J]. Chinese Journal of Geology,2003,38(4):470−477
[73] 姜波,李明,宋昱,等. 构造煤及其瓦斯地质意义[M]. 北京:科学出版社,2020.
[74] LIU Hewu,JIANG Bo. Stress response of noncovalent bonds in molecular networks of tectonically deformed coals[J]. Fuel,2019,255:115785.
[75] SONG Yu,JIANG Bo,HAN Yuzhen. Macromolecular response to tectonic deformation in low–rank tectonically deformed coals (TDCs)[J]. Fuel,2018,219:279−287.
[76] 琚宜文,姜波,侯泉林,等. 构造煤结构–成因新分类及其地质意义[J]. 煤炭学报,2004,29(5):513−517 JU Yiwen,JIANG Bo,HOU Quanlin,et al. The new structure–genetic classification system in tectonically deformed coals and its geological significance[J]. Journal of China Coal Society,2004,29(5):513−517
[77] 琚宜文,姜波,侯泉林,等. 构造煤13CNMR谱及其结构成分的应力效应[J]. 中国科学(D辑:地球科学),2005,35(9):847−861
[78] KHATIBI S,OSTADHASSAN M,TUSCHEL D,et al. Raman spectroscopy to study thermal maturity and elastic modulus of kerogen[J]. International Journal of Coal Geology,2018,185:103−118.
[79] TAN Xinyu,GILLILAND E,TANG Xu,et al. Integrated experimental characterization of shales of varying thermal maturation in the central Appalachian Basin using Raman and Fourier transform infrared spectroscopy and atomic force microscopy[J]. Energy & Fuels,2021,35(1):201−212.
[80] EMMANUEL S,ELIYAHU M,DAY–STIRRAT R J,et al. Impact of thermal maturation on nano–scale elastic properties of organic matter in shales[J]. Marine and Petroleum Geology,2016,70:175−184.
[81] PAN Jienan,MENG Zhaoping,HOU Quanlin,et al. Coal strength and Young’s modulus related to coal rank,compressional velocity and maceral composition[J]. Journal of Structural Geology,2013,54:129−135.
[82] 侯晨亮,姜波,李明,等. 构造煤中有机显微组分变形差异的力学及分子结构本质[J]. 煤炭学报,2025,50(3):1633−1646 HOU Chenliang,JIANG Bo,LI Ming,et al. Mechanical and molecular structure essence of deformation differences in organic macerals of tectonically deformed coal[J]. Journal of China Coal Society,2025,50(3):1633−1646
[83] ZHANG Ningyuan,YAO Suping,WANG Yuhui. Nanopore structure and mechanical properties in brittle tectonically deformed coals explored by atomic force microscopy[J]. Frontiers in Earth Science,2022,10:844120.
[84] WANG Anmin,CAO Daiyong,WEI Yingchun,et al. Macromolecular structure controlling micro mechanical properties of vitrinite and inertinite in tectonically deformed coals:A case study in Fengfeng coal mine of Taihangshan fault zone (North China)[J]. Energies,2020,13(24):6618.
[85] 林治穆. 煤的反射率[J]. 煤炭工程师,1988,15(2):22−25
[86] 杨起. 煤变质作用研究[J]. 现代地质,1992,6(4):437−443 YANG Qi. The study of coal metamorphism[J]. Geoscience,1992,6(4):437−443
[87] 姜波,秦勇. 变形煤镜质组反射率演化的地化机理及其地质意义[J]. 煤田地质与勘探,1999,27(5):19−22 JIANG Bo,QIN Yong. Geochemical mechanism of evolution of vitrinite reflectance of deformed coals and its geological significance[J]. Coal Geology & Exploration,1999,27(5):19−22
[88] 曲星武,王金城. 煤的X射线分析[J]. 煤田地质与勘探,1980,8(2):33−40
[89] STONE I J,COOK A C. The influence of some tectonic structures upon vitrinite reflectance[J]. The Journal of Geology,1979,87(5):497−508.
[90] COOK A C,MURCHISON D G,SCOTT E. Optically biaxial anthracitic vitrinites[J]. Fuel,1972,51(3):180−184.
[91] ROSS J V,BUSTIN R M. Vitrinite anisotropy resulting from simple shear experiments at high temperature and high confining pressure[J]. International Journal of Coal Geology,1997,33(2):153−168.
[92] 王文侠. 湖南金竹山–渣渡矿区煤反射率的有限应变分析[J]. 中国矿业学院学报,1987,16(4):62−68 WANG Wenxia. The finite–strain analysis for the coal reflectance in Jinzhushan–Zhadu coalfield,Hunan Province[J]. Journal of China University of Mining & Technology,1987,16(4):62−68
[93] 王文侠. 涟源煤田无烟煤镜质组反射率的异性组构与有限应变分析[J]. 煤炭学报,1991,16(2):94−102 WANG Wenxia. The analyses of anisotropic fabric and finite strain for vitrinite reflectance of anthracite in Lianyuan coal field,Hunan[J]. Journal of China Coal Society,1991,16(2):94−102
[94] 曹代勇. 安徽淮北煤田推覆构造中煤镜质组反射率各向异性研究[J]. 地质论评,1990,36(4):333−340 CAO Daiyong. The vitrinite reflectance anisotropy in the nappe structure in the Huaibei coalfield,Anhui Province[J]. Geological Review,1990,36(4):333−340
[95] 顾广鉴. 山东石炭二迭系煤的变质因素浅见[J]. 煤田地质与勘探,1977,5(2):66−72
[96] 许孝庭. 淮北煤田石炭二叠纪煤的变质作用概析[J]. 煤田地质与勘探,1986,14(2):23−25
[97] 郑明焕. 煤质评价的几个问题[J]. 地质月刊,1959(3):36−39
[98] 孫以諫. 关于煤分類及其他問題[J]. 地质论评,1957,17(4):441−450
[99] SONG Yu,JIANG Bo,LIU Hewu,et al. Variations in stress–sensitive minerals and elements in the tectonic–deformation Early to Middle Permian coals from the Zhuxianzhuang mine,Anhui Province[J]. Journal of Geochemical Exploration,2018,188:11−23.
[100] 程国玺,姜波,刘和平,等. 构造煤变形过程中矿物及元素响应:以朱仙庄矿8号煤为例[J]. 煤炭学报,2017,42(4):985−995 CHENG Guoxi,JIANG Bo,LIU Heping,et al. Response of minerals and elements during coal deformation:Taking Zhuxianzhuang mine No. 8 coal as an example[J]. Journal of China Coal Society,2017,42(4):985−995
[101] 李云波. 构造煤中应力敏感元素迁移聚集规律及动力学机制:以淮北矿区为例[D]. 徐州:中国矿业大学,2014. LI Yunbo. Tectonic dynamic mechanism of tectonical–sensitive elements’ migration and aggregation in tectonically deformed coal:An example from the Huaibei coalfield,China[D]. Xuzhou:China University of Mining and Technology,2014.
[102] 李云波,姜波,屈争辉. 构造煤中敏感元素迁移、聚集规律及地质控制因素:以淮北海孜矿为例[J]. 中国科学:地球科学,2014,44(11):2419−2430 LI Yunbo,JIANG Bo,QU Zhenghui. Controls on migration and aggregation for tectonically sensitive elements in tectonically deformed coal:An example from the Haizi mine,Huaibei coalfield,China[J]. Science China:Earth Sciences,2014,44(11):2419−2430
[103] 姜波,李云波,屈争辉,等. 瓦斯突出预测构造–地球化学理论与方法初探[J]. 煤炭学报,2015,40(6):1408−1414 JIANG Bo,LI Yunbo,QU Zhenghui,et al. Preliminary study on theory and method of structural geochemistry of gas outburst prediction[J]. Journal of China Coal Society,2015,40(6):1408−1414
[104] 刘和武. 构造煤中应力敏感元素与矿物动力分异特征及机理研究[D]. 徐州:中国矿业大学,2020. LIU Hewu. The dynamic differentiation characteristics and mechanisms of stress–sensitive elements and minerals in tectonically deformed coals[D]. Xuzhou:China University of Mining and Technology,2020.
[105] 刘和平. 煤变形过程中矿物及元素响应特征:以朱仙庄矿为例[D]. 徐州:中国矿业大学,2016. LIU Heping. Response characteristics of minerals and elements during coal deformation:Taking Zhuxianzhuang mine as an example[D]. Xuzhou:China University of Mining and Technology,2016.
[106] 李明,姜波,秦勇,等. 构造煤中矿物质对孔隙结构的影响研究[J]. 煤炭学报,2017,42(3):726−731 LI Ming,JIANG Bo,QIN Yong,et al. Analysis of mineral effect on coal pore structure of tectonically deformed coal[J]. Journal of China Coal Society,2017,42(3):726−731
[107] 李云波,姜波. 淮北宿临矿区构造煤中硫的分布规律及赋存机制[J]. 煤炭学报,2015,40(2):412−421 LI Yunbo,JIANG Bo. Sulfur distribution and occurrence pattern in tectonically deformed coal from Sulin coalfield,Anhui Province[J]. Journal of China Coal Society,2015,40(2):412−421
[108] 李云波,姜波,屈争辉. 淮北宿临矿区构造煤中黄铁矿赋存特征及其地质控制[J]. 地质科学,2017,52(3):855−870 LI Yunbo,JIANG Bo,QU Zhenghui. Pyrite occurrence characteristics and geological control in tectonically deformed coal from the Linsu mining area,Huaibei coalfield,China[J]. Chinese Journal of Geology,2017,52(3):855−870
[109] 张代钧. 煤结构与煤变质程度关系初探[J]. 煤田地质与勘探,1989,17(5):22−26
[110] 侯泉林,雒毅,宋超,等. 中煤级煤变形产气过程及其机理探讨[J]. 煤炭学报,2014,39(8):1675−1682 HOU Quanlin,LUO Yi,SONG Chao,et al. Gas generation during middle–rank coal deformation and the preliminary discussion of the mechanism[J]. Journal of China Coal Society,2014,39(8):1675−1682
[111] 曲星武,王金城. 煤的结构与变质因素的关系[J]. 煤田地质与勘探,1980,8(3):20−28
[112] 张小兵,王蔚,张玉贵,等. 构造煤微晶取向生长机制探讨[J]. 煤炭学报,2016,41(3):712−718 ZHANG Xiaobing,WANG Wei,ZHANG Yugui,et al. Oriented growth mechanism of tectonic coal microcrystal[J]. Journal of China Coal Society,2016,41(3):712−718
[113] 周贺,潘结南,李猛,等. 不同变质变形煤微晶结构的XRD试验研究[J]. 河南理工大学学报(自然科学版),2019,38(1):26−35 ZHOU He,PAN Jienan,LI Meng,et al. Study on microcrystalline structures of different metamorphic and deformed coals based on XRD experiments[J]. Journal of Henan Polytechnic University (Natural Science),2019,38(1):26−35
[114] 郭德勇,郭晓洁,刘庆军,等. 烟煤级构造煤分子结构演化及动力变质作用研究[J]. 中国矿业大学学报,2019,48(5):1036−1044 GUO Deyong,GUO Xiaojie,LIU Qingjun,et al. Study of molecular structure evolution and dynamic metamorphism of bituminous deformed coal[J]. Journal of China University of Mining & Technology,2019,48(5):1036−1044
[115] 郭德勇,韩德馨. 构造煤的电子顺磁共振实验研究[J]. 中国矿业大学学报,1999,28(1):94−97 GUO Deyong,HAN Dexin. Electron paramagnetic resonance studies of the structurally disturbed coals[J]. Journal of China University of Mining & Technology,1999,28(1):94−97
[116] 郭德勇,叶建伟,王启宝,等. 平顶山矿区构造煤傅里叶红外光谱和13C核磁共振研究[J]. 煤炭学报,2016,41(12):3040−3046 GUO Deyong,YE Jianwei,WANG Qibao,et al. FTIR and 13C NMR characterizations for deformed coal in Pingdingshan mining[J]. Journal of China Coal Society,2016,41(12):3040−3046
[117] 李小明,曹代勇,张守仁,等. 构造煤与原生结构煤的显微傅立叶红外光谱特征对比研究[J]. 中国煤田地质,2005,17(3):9−11 LI Xiaoming,CAO Daiyong,ZHANG Shouren,et al. Contrast study on the micro–FTIR characters between deformed and undeformed coals[J]. Coal Geology of China,2005,17(3):9−11
[118] 姬新强,要惠芳,李伟. 韩城矿区构造煤红外光谱特征研究[J]. 煤炭学报,2016,41(8):2050−2056 JI Xinqiang,YAO Huifang,LI Wei. FTIR spectroscopic study on tectonically deformed coals in Hancheng mining area[J]. Journal of China Coal Society,2016,41(8):2050−2056
[119] 刘和武,吕晓雪,侯晨亮,等. 动力变质作用对构造煤微纳米孔隙结构演化的影响机理[J]. 煤田地质与勘探,2024,52(12):1−12 LIU Hewu,LYU Xiaoxue,HOU Chenliang,et al. Influence mechanisms of dynamic metamorphism on the evolution of micro/nano pore structures in tectonically deformed coals[J]. Coal Geology & Exploration,2024,52(12):1−12
[120] LIU Xianfeng,SONG Dazhao,HE Xueqiu,et al. Insight into the macromolecular structural differences between hard coal and deformed soft coal[J]. Fuel,2019,245:188−197.
[121] PAN Jienan,LYU Minmin,BAI Heling,et al. Effects of metamorphism and deformation on the coal macromolecular structure by laser Raman spectroscopy[J]. Energy & Fuels,2017,31(2):1136−1146.
[122] SONG Yu,JIANG Bo,QU Meijun. Macromolecular evolution and structural defects in tectonically deformed coals[J]. Fuel,2019,236:1432−1445.
[123] 郭德勇,郭晓洁,陈培红,等. 构造煤分子结构的动力损伤对瓦斯吸附的影响[J]. 煤炭学报,2020,45(7):2610−2618 GUO Deyong,GUO Xiaojie,CHEN Peihong,et al. Influence of dynamic damage of deformed coal molecular structure on methane adsorption[J]. Journal of China Coal Society,2020,45(7):2610−2618
[124] 张玉贵,张子敏,张小兵,等. 构造煤演化的力化学作用机制[J]. 中国煤炭地质,2008,20(10):11−13 ZHANG Yugui,ZHANG Zimin,ZHANG Xiaobing,et al. Mechanochemical action mechanism of tectonically deformed coal evolvement[J]. Coal Geology of China,2008,20(10):11−13
[125] 张小兵,张子敏,张玉贵. 力化学作用与构造煤结构[J]. 中国煤炭地质,2009,21(2):10−14 ZHANG Xiaobing,ZHANG Zimin,ZHANG Yugui. Mechanochemical action and deformed coal structure[J]. Coal Geology of China,2009,21(2):10−14
[126] SONG Yu,JIANG Bo,LI Ming,et al. Macromolecular transformations for tectonically–deformed high volatile bituminous via HRTEM and XRD analyses[J]. Fuel,2020,263:116756.
[127] PAN Jienan,WANG Sen,JU Yiwen,et al. Quantitative study of the macromolecular structures of tectonically deformed coal using high–resolution transmission electron microscopy[J]. Journal of Natural Gas Science and Engineering,2015,27:1852−1862.
[128] YANG Wenbin,SONG Yu,LI Wu. Nanostructural characteristic changes in high–volatile bituminous coal in response to differential tectonic deformation:Insights gained from quantified HRTEM aromatic fringes[J]. Energy & Fuels,2023,37(14):10166−10176.
[129] LI Yunbo,SONG Dangyu,LIU Shimin,et al. Characterization of ultramicropores and analysis of their evolution in tectonically deformed coals by low–pressure CO2 adsorption,XRD,and HRTEM techniques[J]. Energy & Fuels,2020,34(8):9436−9449.
[130] 朱海涛. 基于AFM的不同变质变形煤的超微结构研究[D]. 焦作:河南理工大学,2014. ZHU Haitao. Study on the microstructure of different metamorphic deformed coal based on AFM[D]. Jiaozuo:Henan Polytechnic University,2014.
[131] 张玉贵,张子敏,郭明功. 溶剂萃取法研究平顶山构造煤结构与瓦斯突出[C]//中国煤炭学会瓦斯地质专业委员会第五次全国瓦斯地质学术研讨会. 长春:中国煤炭学会,2004:219–223.
[132] 麻志浩,阳虹,张玉贵,等. 构造煤萃取物光谱特征与排烃层析效应[J]. 煤炭转化,2016,39(2):11−19 MA Zhihao,YANG Hong,ZHANG Yugui,et al. Extract spectral feature of tectonic coal and hydrocarbon chromatography effect[J]. Coal Conversion,2016,39(2):11−19
[133] 杨延辉,张小东,杨艳磊,等. 溶剂萃取后构造煤的微晶及化学结构参数变化特征[J]. 煤炭学报,2016,41(10):2638−2644 YANG Yanhui,ZHANG Xiaodong,YANG Yanlei,et al. Change characteristics of microcrystalline and chemical structure parameters of tectonic coals under solvents extraction[J]. Journal of China Coal Society,2016,41(10):2638−2644
[134] CARLSON G A. Computer simulation of the molecular structure of bituminous coal[J]. Energy & Fuels,1992,6(6):771−778.
[135] 陈皓侃,李保庆,李文. 分子力学和分子动力学方法研究不同变质程度烟煤的分子结构[J]. 燃料化学学报,2000,28(5):459−462 CHEN Haokan,LI Baoqing,LI Wen. Modeling of molecular structure of various bituminous coals by molecular mechanics and molecular dynamics[J]. Journal of Fuel Chemistry and Technology,2000,28(5):459−462
[136] XU Rongting,LI Huijun,GUO Chenchen,et al. The mechanisms of gas generation during coal deformation:Preliminary observations[J]. Fuel,2014,117:326−330.
[137] HAN Yuzhen,XU Rongting,HOU Quanlin,et al. Deformation mechanisms and macromolecular structure response of anthracite under different stress[J]. Energy & Fuels,2016,30(2):975−983.
[138] 张婧祺,郝奇,吕国建,等. 基于微观结构非均匀性理解非晶态聚苯乙烯的应力松弛行为[J]. 物理学报,2024,73(3):037601 ZHANG Jingqi,HAO Qi,LYU Guojian,et al. Understanding stress relaxation behavior of amorphous polystyrene based on microstructural heterogeneity[J]. Acta Physica Sinica,2024,73(3):037601
[139] 解鸿偲. 高熵合金/石墨烯复合材料力学行为的分子动力学研究[D]. 长春:吉林大学,2024. XIE Hongsi. Molecular dynamics study on the mechanical behavior of high–entropy alloy/graphene composites[D]. Changchun:Jilin University,2024.
[140] 王晨阳,邓涛. 交联网络状态对CR硫化胶应力松弛的影响[J]. 特种橡胶制品,2023,44(3):14−18 WANG Chenyang,DENG Tao. Effect of crosslinking network state on stress relaxation of chloroprene rubber vulcanizates[J]. Special Purpose Rubber Products,2023,44(3):14−18
[141] VAN HEEK K H. Progress of coal science in the 20th century[J]. Fuel,2000,79(1):1−26.
[142] 琚宜文,李小诗. 构造煤超微结构研究新进展[J]. 自然科学进展,2009,19(2):131−140
[143] 秦匡宗,郭绍辉,李术元. 煤结构的新概念与煤成油机理的再认识[J]. 科学通报,1998,43(18):1912−1918
[144] NISHIOKA M,LARSEN J W. Association of aromatic structures in coals[J]. Energy & Fuels,1990,4(1):100−106.
[145] 琚宜文,姜波,侯泉林,等. 煤岩结构纳米级变形与变质变形环境的关系[J]. 科学通报,2005,50(17):1884−1892
[146] WANG Jin,HOU Quanlin,ZENG Fangui,et al. Gas generation mechanisms of bituminous coal under shear stress based on ReaxFF molecular dynamics simulation[J]. Fuel,2021,298:120240.
[147] 刘文汇. 值得重视的有机质演化营力成烃的力化学作用[J]. 天然气地球科学,1995,6(4):1−7
[148] WANG Jin,HOU Quanlin,ZENG Fangui,et al. Stress sensitivity for the occurrence of coalbed gas outbursts:A reactive force field molecular dynamics study[J]. Energy & Fuels,2021,35(7):5801−5807.
[149] WANG Jin,GUO Guangjun,HAN Yuzhen,et al. Mechanolysis mechanisms of the fused aromatic rings of anthracite coal under shear stress[J]. Fuel,2019,253:1247−1255.
[150] WANG Jin,HAN Yuzhen,CHEN Bozhen,et al. Mechanisms of methane generation from anthracite at low temperatures:Insights from quantum chemistry calculations[J]. International Journal of Hydrogen Energy,2017,42(30):18922−18929.
[151] XU Rongting,LI Huijun,HOU Quanlin,et al. The effect of different deformation mechanisms on the chemical structure of anthracite coals[J]. Science China Earth Sciences,2015,58(4):502−509.
[152] HAN Yuzhen,WANG Jin,DONG Yijing,et al. The role of structure defects in the deformation of anthracite and their influence on the macromolecular structure[J]. Fuel,2017,206:1−9.
[153] 秦勇,姜波,曾勇,等. 中国高煤级煤EPR阶跃式演化及地球化学意义[J]. 中国科学(D辑:地球科学),1997,27(6):499−502
[154] LIU Lili,QING Miaoqing,WANG Yibo,et al. Defects in graphene:Generation,healing,and their effects on the properties of graphene:A review[J]. Journal of Materials Science & Technology,2015,31(6):599−606.
[155] LI Xiaoshi,JU Yiwen,HOU Quanlin,et al. Characterization of coal porosity for naturally tectonically stressed coals in Huaibei coal field,China[J]. The Scientific World Journal,2014,2014(1):560450.
[156] LIU Hewu,JIANG Bo,SONG Yu,et al. The tectonic stress–driving alteration and evolution of chemical structure for low– to medium–rank coals:By molecular simulation method[J]. Arabian Journal of Geosciences,2019,12(23):726.
[157] LIU Hewu,SONG Yu,DU Zhigang. Molecular dynamics simulation of shear friction process in tectonically deformed coal[J]. Frontiers in Earth Science,2023,10:1030501.
[158] LIU Hewu,HOU Chenliang. The role of non–covalent bonds in the deformation process of coal:An experimental study on bituminous coal[J]. Processes,2022,10(9):1875.
[159] QIU Xu,SANG Yueqian,WU Hao,et al. Cleaving arene rings for acyclic alkenylnitrile synthesis[J]. Nature,2021,597(7874):64−69.
[160] 刘诗哲. 甲基环己烷脱氢催化体系的研究进展[J]. 化工进展,2025,44(6):3486−3496 LIU Shizhe. Advances in catalytic system for methylcyclohexane dehydrogenation[J]. Chemical Industry and Engineering Progress,2025,44(6):3486−3496
[161] 刘文汇. 油气形成的力化学作用:油气地质理论思考之一[J]. 地球科学进展,1999,14(4):340−345 LIU Wenhui. The mechanochemistry in formation of oil and gas:The first of thoughts to the theory of petroleum formation[J]. Advances in Earth Science,1999,14(4):340−345
[162] HOU Quanlin,HAN Yuzhen,WANG Jin,et al. The impacts of stress on the chemical structure of coals:A mini–review based on the recent development of mechanochemistry[J]. Science Bulletin,2017,62(13):965−970.
[163] CHENG Nannan,PAN Jienan,SHI Mengyan,et al. The impacts of stress on the macromolecular structure of anthracites:Implications for the mechanochemical effects[J]. International Journal of Coal Geology,2022,264:104151.
[164] 曹代勇,王路,刘志飞,等. 我国煤系石墨研究及资源开发利用前景[J]. 煤田地质与勘探,2020,48(1):1−11 CAO Daiyong,WANG Lu,LIU Zhifei,et al. The research status and prospect of coal–based graphite in China[J]. Coal Geology & Exploration,2020,48(1):1−11
[165] 秦勇,金奎励,韩德馨. 滇西腾冲盆地晚更新世软褐煤的发现及其意义[J]. 科学通报,1995,40(3):247−249
[166] 秦勇,曹作华. 豫西高煤级煤中有机元素及统计结构的演化与煤化作用跃变[J]. 焦作矿业学院学报,1993,12(4):22−29 QIN Yong,CAO Zuohua. Evolution of the organic elements and the statistical structures and coalification jumps of the high–rank coals from the north–western Henan,China[J]. Journal of Jiaozuo Mining Institute,1993,12(4):22−29
[167] 张代钧,鲜学福. 煤大分子结构研究的进展[J]. 重庆大学学报,1993(2):58−63 ZHANG Daijun,XIAN Xuefu. The advance in the study of the macromolecular structure of coals[J]. Journal of Chongqing University,1993(2):58−63
[168] 张玉贵,唐修义,何萍. 煤的分子结构与煤的自燃倾向性[J]. 煤矿安全,1992,23(5):1−4
[169] 李小诗,琚宜文,侯泉林,等. 构造变形作用对煤岩大分子结构的影响:以构造煤镜质组分离为例[J]. 煤炭学报,2010,35(增刊1):150−157 LI Xiaoshi,JU Yiwen,HOU Quanlin,et al. Influence mechanism of tectonic deformation on macromolecular chemical structure of coals:A case study of vitrinite separation of tectonically deformed coals[J]. Journal of China Coal Society,2010,35(Sup.1):150−157
[170] 李小诗,琚宜文,侯泉林,等. 煤岩变质变形作用的谱学研究[J]. 光谱学与光谱分析,2011,31(8):2176−2182 LI Xiaoshi,JU Yiwen,HOU Quanlin,et al. Spectrum research on metamorphic and deformation of tectonically deformed coals[J]. Spectroscopy and Spectral Analysis,2011,31(8):2176−2182
[171] 王绍清,王小令,沙吉顿,等. 煤石墨化:结构和差异性演化[J]. 煤炭学报,2022,47(12):4300−4312 WANG Shaoqing,WANG Xiaoling,SHA Jidun,et al. Coal graphitization:Structures and their differential evolution[J]. Journal of China
Included in
Earth Sciences Commons, Mining Engineering Commons, Oil, Gas, and Energy Commons, Sustainability Commons