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Coal Geology & Exploration

Abstract

Most of the coal seams in China are characterized by low pressure, low permeability and low saturation. The methane gas in the coal seam is slowly desorbed and diffused slowly, which affects the production rate of coalbed methane. The coal samples from Zhaozhuang Coal Mine of Jinmei Group were selected to study the influence of different gas injection pressure on CH4 displacement process and the variation law of CH4 diffusion coefficient in the process of displacement. Independently developed CO2 displacement CH4 test platform was used to carry out the experiments under different gas injection pressures such as 0.6, 0.8 and 1.0 MPa. The results show that the greater the displacement pressure, the shorter the time to reach the maximum CH4 emission, the faster the breakthrough time of CO2, the greater the displacement efficiency and the better the displacement effect. The process of CH4 gas displacement can be divided into three stages, first increasing sharply, then slowly increasing, and finally keeping stable. Under the same gas injection pressure, the gas diffusion coefficient first increases and then decreases with time. When the gas injection pressure is 0.6, 0.8 and 1.0 MPa, the corresponding maximum values of gas diffusion coefficient are respectively 2.27×10-5, 3.36×10-5, 4.62×10-5 cm2/s. According to the experimental results, CO2 plays an important role in CH4 displacement, displacement adsorption-desorption and dilution displacement under different gas injection pressures. The migration of CH4 gas in each stage is different, so the injection-gas flow rate, pressure and other parameters can be reasonably adjusted according to the corresponding migration of CH4 gas in the experimental stage to make the injection and flooding technology collocation more efficient. The research results present a theoretical guidance for deep CO2 burial and efficient gas extraction(CBM).

Keywords

CO2 breakthrough time, gas injection displacement, displacement efficiency, effective diffusion coefficient, Qinshui Basin

DOI

10.3969/j.issn.1001-1986.2021.01.008

Reference

[1] 涂敏. 低渗透性煤层群卸压开采地面钻井抽采瓦斯技术[J]. 采矿与安全工程学报,2013,30(5):766-772. TU Min. Surface well drilling extracting gas technology in low permeability coal seams depressurized mining[J]. Journal of Mining & Safety Engineering,2013,30(5):766-772.

[2] 叶建平,陆小霞. 我国煤层气产业发展现状和技术进展[J]. 煤炭科学技术,2016,44(1):24-28. YE Jianping,LU Xiaoxia. Development status and technical progress of China coalbed methane industry[J]. Coal Science and Technology,2016,44(1):24-28.

[3] 王瑞雪. 不同变质程度煤对CH4和CO2吸附特征差异的实验研究[D]. 徐州:中国矿业大学,2020. WANG Ruixue. Experimental study on the adsorption characteristics of CH4 and CO2 by coal with different metamorphic degree[D]. Xuzhou:China University of Mining and Technology,2020.

[4] 杨宏民,王兆丰,任子阳. 煤中二元气体竞争吸附与置换解吸的差异性及其置换规律[J]. 煤炭学报,2015,40(7):1550-1554. YANG Hongmin,WANG Zhaofeng,REN Ziyang. Difference between competitive adsorption and replacement desorption of binary gas in coal and its replacement law[J]. Journal of China Coal Society,2015,40(7):1550-1554.

[5] 周俊文. 二氧化碳驱替煤层甲烷的试验研究[J]. 能源与环保,2019,41(1):13-16. ZHOU Junwen. Study on test of displacement coal-bed methane by carbon dioxide[J]. China Energy and Environmental Protection,2019,41(1):13-16.

[6] 李菁华,张磊,薛俊华,等. 注气驱替中CO2置换煤体CH4行为特性[J/OL].煤炭学报:1-11[2020-10-16]. https://doi.org/10.13225/j.cnki.jccs.2020.1134. LI Jinghua,ZHANG Lei,XUE Junhua,et al. Experimental study on the characteristic of binary gas displacement adsorption on coal in CO2-ECBM[J/OL]. Journal of China Coal Society:1-11[2020-10-16] https://doi.org/10.13225/j.cnki.jccs.2020.1134.

[7] 白云云,张永成. CO2-ECBM技术的利弊分析[J]. 石油化工应用,2017,36(1):3-6. BAI Yunyun,ZHANG Yongcheng. Analysis of advantages and disadvantages on CO2-ECBM technology[J]. Petrochemical Industry Application,2017,36(1):3-6.

[8] WHITE C M,SMITH D H,JONES K L,et al. Sequestration of carbon dioxide in coal with enhanced coalbed methane recovery:A review[J]. Energy & Fuels,2005,19:659-724.

[9] GEORGE S,BARAKAT M. The change in effective stress associated with shrinkage from gas desorption in coal[J]. International Journal of Coal Geology,2001,69(6):83-115.

[10] PAN Zhejun,CONNELL L D. A theoretical model for gas adsorption-induced coal swelling[J]. International Journal of Coal Geology,2007,69:243-252.

[11] 张琨,桑树勋,刘长江. 深部煤层CO2注入过程中煤体积参数变化的模拟实验[J]. 煤田地质与勘探,2018,46(5):26-31. ZHANG Kun,SANG Shuxun,LIU Changjiang. Simulation experiment on the changes of CO2 burial process in deep coal seam[J]. Coal Geology & Exploration,2018,46(5):26-31.

[12] 牛庆合,曹丽文,周效志. CO2注入对煤储层应力应变与渗透率影响的实验研究[J]. 煤田地质与勘探,2018,46(5):43-48. NIU Qinghe,CAO Liwen,ZHOU Xiaozhi. Experimental study of the influences of CO2 injection on stress-strain and permeability of coal reservoir[J]. Coal Geology & Exploration,2018,46(5):43-48.

[13] 吴迪,刘雪莹,孙可明,等. 含CH4煤岩注CO2后力学性能及渗透性能试验研究[J]. 中国安全科学学报,2015,25(11):106-110. WU Di,LIU Xueying,SUN Keming,et al. Research on mechanical properties and permeability of gas-containing coal injected with CO2[J]. China Safety Science Journal,2015,25(11):106-110.

[14] 邓军,任立峰,吴明明,等. 低透煤层CO2相变致裂增透解吸技术的应用[J]. 西安科技大学学报,2018,38(5):24-27. DENG Jun,REN Lifeng,WU Mingming,et al. Desorption experiments and thermodynamic parameters of coal for CO2[J]. Journal of Xi'an University of Science and Technology,2018,38(5):24-27.

[15] 何学秋,聂百胜. 孔隙气体在煤层中扩散的机理[J]. 中国矿业大学学报,2001,30(1):3-6. HE Xueqiu,NIE Baisheng. Diffusion mechanism of porous gases in coal seams[J]. Journal of China University of Mining & Technology,2001,30(1):3-6.

[16] 李前贵,康毅力,罗平亚. 煤层甲烷解吸-扩散-渗流过程的影响因素分析[J]. 煤田地质与勘探,2003,31(4):26-29. LI Qiangui,KANG Yili,LUO Pingya. Analysis of the factors affecting processes of CBM desorption,diffusion and percolation[J]. Coal Geology & Exploration,2003,31(4):26-29.

[17] 李祥春,李忠备,张良,等. 不同煤阶煤样孔隙结构表征及其对瓦斯解吸扩散的影响[J]. 煤炭学报,2019,44(增刊1):142-156. LI Xiangchun,LI Zhongbei,ZHANG Liang,et al. Pore structure characterization of various rank coals and its effect on gas desorption and diffusion[J]. Journal of China Coal Society,2019,44(Sup.1):142-156.

[18] 杨宏民,梁龙辉,冯朝阳,等. 注气压力对不同注源气体置驱效应的影响[J]. 中国安全科学学报,2017,27(9):122-128.YANG Hongmin,LIANG Longhui,FENG Chaoyang,et al. Study on influence of injection pressure on replacement effect for different injection gases[J]. China Safety Science Journal,2017,27(9):122-128.

[19] 杨鑫,张俊英,王公达,等. 瓦斯压力对瓦斯在煤中扩散影响的实验研究[J]. 中国矿业大学学报,2019,48(3):503-510. YANG Xin,ZHANG Junying,WANG Gongda,et al. Experimental study of the influence of gas pressure on the gas diffusion in coal[J]. Journal of China University of Mining & Technology,2019,48(3):503-510.

[20] 杨其銮,王佑安. 煤屑瓦斯扩散理论及其应用[J]. 煤炭学报,1986,11(3):87-93. YANG Qiluan,WANG You'an. Theory of methane diffusion from coal cuttings and its application[J]. Journal of China Coal Society,1986,11(3):87-93.

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