•  
  •  
 

Coal Geology & Exploration

Abstract

In order to analyze the carbon and oxygen composition and origin of the coal seam gas(CSG) in abandoned mines, Panzhuang block, south of Qinshui basin, in this paper, the coalbed methane and produced water samples were collected. The results show that the CSG of abandoned mines is dominated by CH4, the average is 91.99%, with minor amounts of N2(6.73%) and CO2(1.26%). The δ13C values of CH4 range from -31.36‰ to -33.53‰, with an average of -32.25‰, the hydrogen isotope(δD) value is between -182.76‰ and -193.20‰, and the average value is -187.538‰. The main ions in produced water of abandoned mine are mainly composed of Mg2+, K+, HCO3-, Cl-, Na+, SO42- and NO3-, and the type is Mg-(HCO3)2. The CH4 was mainly generated from thermal cracking during coalification, with some microbial genetic methane. Compared with the unexploited coal seams, the abandoned coal mine is more suitable for methanogen to produce the CH4.

Keywords

abandoned coal mine, coalbed methane(CBM), carbon and oxygen isotope, origin, microbial methane

DOI

10.3969/j.issn.1001-1986.2019.06.011

Reference

[1] CREEDY D P,TILLEY H. Coalbed methane extraction and utilization[J]. Journal of Power and Energy,2003,217(1):19-26.

[2] RAUDSEPP M J,FLUGGEN M,SHYPANSKI A H,et al. Biogenic methane cycling in a laboratory model of an aban-doned bituminous coal mine[J]. Geomicrobiology Journal,2018,35(6):491-502.

[3] 孟召平,师修昌,刘珊珊,等. 废弃煤矿采空区煤层气资源评价模型及应用[J]. 煤炭学报,2016,41(3):537-544. MENG Zhaoping,SHI Xiuchang,LIU Shanshan,et al. Evaluation model of CBM resources in abandoned coal mine and its application[J]. Journal of China Coal Society,2016,41(3):537-544.

[4] KARACAN C Ö. Modeling and analysis of gas capture from sealed sections of abandoned coal mines[J]. International Journal of Coal Geology,2015,138:30-41.

[5] 韩保山,张新民,张群. 废弃矿井煤层气资源量计算范围研究[J]. 煤田地质与勘探,2004,32(1):29-31. HAN Baoshan,ZHANG Xinmin,ZHANG Qun. Theoretical study on calculation limits of CBM resource of abandoned coal mine[J]. Coal Geology & Exploration,2004,32(1):29-31.

[6] FENG Guorui,HU Shengyong,LI Zhen,et al. Distribution of methane enrichment zone in abandoned coal mine and methane drainage by surface vertical boreholes:A case study from China[J]. Journal of Natural Gas Science and Engineering,2016,34:767-778.

[7] 戴金星,戚厚发. 我国煤成烃气的δ13C-Ro关系[J]. 科学通报,1989,34(9):690-692. DAI Jinxing,QI Houfa. δ13C-Ro correlation of the coal-formed gas in China[J]. Chinese Science Bulletin,1989,34(9):690-692.

[8] RIGHTMIRE C T,EDDY G E,KIRR J N. Coalbed methane resources of the United States[M]. Tulsa,Oklahoma,U.S.A:AAPG,1984.

[9] SCOTT A R,KAISER W R,AYERS W B,et al. Thermogenic and secondary biogenic gases,San Juan basin[J]. AAPG Bulletin,1994,78(8):1186-1209.

[10] 徐占杰,刘钦甫,郑启明,等. 沁水盆地北部太原组煤层气碳同位素特征及成因探讨[J]. 煤炭学报,2016,41(6):1467-1475. XU Zhanjie,LIU Qinfu,ZHENG Qiming,et al. Origins and carbon isotopic composition of coalbed methane and carbon dioxide from Taiyuan Formation,northern Qinshui basin,China[J]. Journal of China Coal Society,2016,41(6):1467-1475.

[11] SU Xianbo,LIN Xiaoying,LIU Shaobo,et al. Geology of coalbed methane reservoirs in the southeast Qinshui basin of China[J]. International Journal of Coal Geology,2005,62(4):197-210.

[12] 岳梅,赵峰华,任德贻. 煤矿酸性水水化学特征及其环境地球化学信息研究[J]. 煤田地质与勘探,2004,32(3):46-49. YUE Mei,ZHAO Fenghua,REN Deyi. The environment geochemistry information of the coal mine acid mining drainage[J]. Coal Geology & Exploration,2004,32(3):46-49.

[13] WHITICAR M J. Carbon and hydrogen isotope systematics of bacterial formation and oxidation of methane[J]. Chemical Geology,1999,161(1/2/3):291-314.

[14] 张建博,陶明信. 煤层甲烷碳同位素在煤层气勘探中的地质意义:以沁水盆地为例[J]. 沉积学报,2000,18(4):611-614. ZHANG Jianbo,TAO Mingxin. Geological significances of coalbed methane carbon isotope in coalbed methane exploration[J]. Acta Sedimentologica Sinica,2000,18(4):611-614.

[15] 秦胜飞,赵靖舟,李梅,等. 水溶天然气运移地球化学示踪:以塔里木盆地和田河气田为例[J]. 地学前缘,2006,13(5):524-532. QIN Shengfei,ZHAO Jingzhou,LI Mei,et al. A case study:Geochemical tracing indices on the migration of water-soluble gases in Hetianhe gas field,Tarim basin[J]. Earth Science Frontiers,2006,13(5):524-532.

[16] 李建军,白培康,毛虎平,等. 郑庄-胡底煤层气地球化学特征及成因探讨[J]. 煤炭学报,2014,39(9):1802-1811. LI Jianjun,BAI Peikang,MAO Huping,et al. Analysis of geochemistry characteristics and its origin of CBM in Zhengzhuang and Hudi blocks[J]. Journal of China Coal Society,2014,39(9):1802-1811.

[17] 孙占学,张文,胡宝群,等. 沁水盆地大地热流与地温场特征[J]. 地球物理学报,2006,49(1):130-134. SUN Zhanxue,ZHANG Wen,HU Baoqun,et al. Features of heat flow and the geothermal field of the Qinshui basin[J]. Chinese Journal of Geophysics,2006,49(1):130-134.

[18] SCHOELL M. The hydrogen and carbon isotopic composi-tion of methane from natural gases of various origins[J]. Geochimica et Cosmochimica Acta,1980,44(5):649-661.

[19] 王尚,董海良,侯卫国,等. 微生物在生物煤层气形成中的作用及影响因素研究进展[J]. 地球与环境,2013,41(4):335-345. WANG Shang,DONG Hailiang,HOU Weiguo,et al. Isotopic and microbiological charicterization of secondary biogenic coalbed methane[J]. Earth and Environment,2013,41(4):335-345.

[20] 沈平,王晓锋,徐茵,等. 我国生物气藏碳、氢同位素特征、形成途径及意义[J]. 沉积学报,2010,28(1):183-187. SHEN Ping,WANG Xiaofeng,XU Yin,et al. Carbon and hydrogen isotopic compositions:Generation pathway of bacterial gas in China[J]. Acta Sedimentologica Sinica,2010,28(1):183-187.

[21] 王晓锋,刘文汇,徐永昌,等. 水介质对气态烃形成演化过程氢同位素组成的影响[J]. 中国科学:地球科学,2012,42(1):103-110. WANG Xiaofeng,LIU Wenhui,XU Yongchang,et al. In-fluences of water media on the hydrogen isotopic composition of natural gas/methane in the processes of gaseous hydrocarbon generation and evolution[J]. Science in China:Earth Science,2012,42(1):103-110.

[22] 邵龙义,肖正辉,汪浩,等. 沁水盆地石炭-二叠纪含煤岩系高分辨率层序地层及聚煤模式[J]. 地质科学,2008,43(4):777-791. SHAO Longyi,XIAO Zhenghui,WANG Hao,et al. Per-mo-Carboniferous coal measures in the Qinshui basin:High-resolution sequence stratigraphy and coal accumulating models[J]. Chinese Journal of Geology,2008,43(4):777-791.

[23] WHITICAR M J,FABER E,SCHOELL M. Biogenic methane formation in marine and freshwater environments:CO2 reduction vs. acetate fermentation:Isotope evidence[J]. Geochimica et Cosmochimica Acta,1986,50(5):693-709.

[24] LI M. Hydrogen isotopic compositions of individual al-kanes as a new approach to petroleum correlation:Case studies from the western Canada sedimentary basin[J]. Organic Geochemistry,2001,32(12):1387-1399.

[25] RICE D D. Composition and origins of coalbed gas hydrocarbons from goal[C]//Hydrocarbons from Coal. Canada:AAPG Special Publication,1993,38:159-184.

[26] 卫明明,琚宜文. 沁水盆地南部煤层气田产出水地球化学特征及其来源研究[J]. 煤炭学报,2015,40(3):629-635. WEI Mingming,JU Yiwen. Chemical characteristics and origin of produced waters from coalbed gas field in the southern of Qinshui basin[J]. Journal of China Coal Society,2015,40(3):629-635.

[27] 刘会虎,兰天贺,胡宝林,等. 淮南潘集外围深部煤层气地球化学特征及成因[J]. 煤炭学报,2018,43(2):498-506. LIU Huihu,LAN Tianhe,HU Baolin,et al. Geochemical characteristics and its origins of CBM in deep-seated coal seam around Panji mining area of Huainan[J]. Journal of China Coal Society,2018,43(2):498-506.

[28] JENDEN P D,KAPLAN I R. Comparison of microbial gases from the middle America trench and scrips submarine Can-yon:Implications for the origin of natural gas[J]. Applied Geochemistry,1986,1(6):631-646.

[29] 戴金星,戚厚发,宋岩,等. 我国煤层气组份、碳同位素类型及其成因和意义[J]. 中国科学:B辑,1986,16(12):1317-1326. DAI Jinxing,QI Houfa,SONG Yan,et al. Compositional,stable carbon isotope,origin and geological significance of coalbed methane in China[J]. Science China:Series B,1986,16(12):1317-1326.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.